Organic chemistry
1. An efficient and one-pot green synthesis of 2-arylsubstituted benzimidazoles catalyzed by nano-Fe3O4@silica sulfuric acid as a recyclable nanomagnetic solid acid catalyst

Mehdi Fallah-Mehrjardi; Manizhe Ayazi; Sayed Hossein Banitaba

Volume 8, Issue 1 , Winter 2020, , Pages 80-91

http://dx.doi.org/10.30473/icc.2019.43207.1493

Abstract
  An efficient and green protocol for the synthesis of 2-arylsubstituted benzimidazoles via a condensation reaction of aromatic aldehydes and 1,2-phenylenediamine using nano-Fe3O4@SiO2-SO3H as a solid acid catalyst in ethanol under reflux conditions has been described. The reactions are completed in short ...  Read More

An efficient and one-pot green synthesis of 2-arylsubstituted benzimidazoles catalyzed by nano-Fe3O4@silica sulfuric acid as a recyclable nanomagnetic solid acid catalyst


Organic chemistry
2. Synthesis of 2-aryl-1H-benzo[d]imidazole derivatives using nano montmorillonite clay as an efficient catalyst

Mohammad Alikarami; Ahmad Nikseresht; Tayebeh Amoozadeh

Volume 8, Issue 1 , Winter 2020, , Pages 42-48

http://dx.doi.org/10.30473/icc.2019.45788.1538

Abstract
  Benzimidazoles are among the most important nitrogen-containing heterocyclic compounds that have many pharmaceutical applications; including, antitumor, anticancer, anticorrosive, antibacterial, irritant and enzymatic interceptors. In this research, the synthesis of benzimidazoles using o-phenylenediamine ...  Read More

Synthesis of 2-aryl-1H-benzo[d]imidazole derivatives using nano montmorillonite clay as an efficient catalyst


Organic chemistry
3. A green and highly effective protocol for the synthesis of N,N′-alkylidene bisamides using saccharin-N-sulfonic acid

Abdolkarim Zare; Manije Dianat; Nasrin Pishahang; Roghayyeh Khanivar; Soheila Kaman-Torki; Fatemeh Fakhraei; Zahra Kordrostami; Masoud Sadeghei-Takallo

Volume 8, Issue 1 , Winter 2020, , Pages 58-66

http://dx.doi.org/10.30473/icc.2019.44250.1514

Abstract
  A green and highly effective solvent-free protocol has been reported for the synthesis of N,N′-alkylidene bisamides via the reaction of arylaldehydes (1 eq.) with primary amides (2 eq.) in the presence of saccharin-N-sulfonic acid (SaSA) as a solid-acid catalyst. The mentioned compounds have been ...  Read More

A green and highly effective protocol for the synthesis of N,N′-alkylidene bisamides using saccharin-N-sulfonic acid


Organic chemistry
4. Ionic liquid anchored to silica (nano-SB-[PSIM]Cl): a highly efficient nanocatalyst for the solvent-free preparation of 1-thioamidolakyl-2-naphthols

Abdolkarim Zare; Manije Dianat; Nahid Varavi; Mina Aali-Hosaini; Hanafieh Deisi

Volume 8, Issue 1 , Winter 2020, , Pages 49-57

http://dx.doi.org/10.30473/icc.2019.43562.1504

Abstract
  Nano-silica-bonded 3-n-propyl-1-sulfonic acid imidazolium chloride (nano-SB-[PSIM]Cl) was applied as a highly efficient, general and heterogeneous catalyst for one pot multi-component reaction of 2-naphthol, arylaldehydes, and thioacetamide leading to 1-thioamidolakyl-2-naphthols. All reactions proceeded ...  Read More

Ionic liquid anchored to silica (nano-SB-[PSIM]Cl): a highly efficient nanocatalyst for the solvent-free preparation of 1-thioamidolakyl-2-naphthols


Organic chemistry
5. Cataliticoxidation of benzyl alcohol by Cu(II) polypyridyl complexes

Ghobad Mansouri

Volume 8, Issue 1 , Winter 2020, , Pages 1-6

http://dx.doi.org/10.30473/icc.2019.47056.1568

Abstract
  Two polypyridyl copper(II) complexes, [Cu(phen)(phen-dione)Cl]Cl (1) and [Cu(bpy) (phen-dione)Cl]Cl (2), (where Phen =1,10-phenanthroline, bpy =2,2'-bipyridine and Phen-dione = 1,10-phenanthroline-5,6-dione), were used as efficient catalysts for the oxidation of benzyl alcohol to benzaldehyde. The effects ...  Read More

Cataliticoxidation of benzyl alcohol by Cu(II) polypyridyl complexes


Organic chemistry
6. Development of ultrasound-assisted emulsification microextraction for the determination of trace zinc and copper by flame atomic absorption spectrometry

Shahryar Abbasi; Mahmoud Roushani; Hadi Noorizadeh

Volume 7, Issue 4. pp. 352-471, Serial No. 25 , Autumn 2019, , Pages 445-454

http://dx.doi.org/10.30473/icc.2019.44276.1516

Abstract
  In this work, we developed a method based on ultrasound-assisted emulsification microextraction (USAEME) for the determination of zinc and copper by flame atomic absorption spectrometry (FAAS). The method is based on the use of the organic solvent carbon tetrachloride (CCl4) as an extraction solvent. ...  Read More

Development of ultrasound-assisted emulsification microextraction for the determination of trace zinc and copper by flame atomic absorption spectrometry


Organic chemistry
7. Photosensitization of coronene–purine hybrids for photodynamic therapy

Amir Hossein Rasouli Amirabadi; Mahmoud Mirzaei

Volume 7, Issue 4. pp. 352-471, Serial No. 25 , Autumn 2019, , Pages 398-404

http://dx.doi.org/10.30473/icc.2019.44075.1511

Abstract
  Photosensitization properties of coronene-purine (Cor-P) hybrids for photodynamic therapy (PDT) have been investigated in this work. Eight hybrid Cor-P models have been designed by the additional of adenine (A) and guanine (G) nucleobase to Cor species. The evaluated absorption and emission energies ...  Read More

Photosensitization of coronene–purine hybrids for photodynamic therapy


Organic chemistry
8. Multi-component synthesis of spiro[indoline-3,4'-pyrrolo[3,4-c]pyrazoles] using Zn(BDC) metal-organic frameworks as a green and efficient catalyst

Masomeh Hoseini Rad; Mohammad Ali Ghasemzadeh; Mahboubeh Sadat Sharif

Volume 7, Issue 4. pp. 352-471, Serial No. 25 , Autumn 2019, , Pages 390-397

http://dx.doi.org/10.30473/icc.2019.42092.1471

Abstract
  In this research, a series of spiro compounds was efficiently synthesized via one-pot multi component reactions of isatins, aryl amines, dimethyl acetylenedicarboxylate and hydrazine in the presence of Zn(BDC) MOF as catalyst. The key superiority of this process is high yields, easy work-up, short reaction ...  Read More

Multi-component synthesis of spiro[indoline-3,4'-pyrrolo[3,4-c]pyrazoles] using Zn(BDC) metal-organic frameworks as a green and efficient catalyst


Organic chemistry
9. Synthesis, characterization, antibacterial activity and molecular modeling studies of Ni(II) and Zn(II) complexes with phenylpyridylformamidine ligand

Ghobad Mansouri; Massoud Ghobadi

Volume 7, Issue 4. pp. 352-471, Serial No. 25 , Autumn 2019, , Pages 424-431

http://dx.doi.org/10.30473/icc.2019.44293.1517

Abstract
  The Ni(II) and Zn(II) complexes with phenylpyridylformamidine (PhPyF) ligand, [Ni(PhPyF)Cl2] and [Zn(PhPyF)Cl2], have been prepared and investigated using different chemical techniques such as elemental analysis, molar conductance, FT-IR, UV-vis spectra and magnetic moment. The obtained chemical analysis ...  Read More

Synthesis, characterization, antibacterial activity and molecular modeling studies of Ni(II) and Zn(II) complexes with phenylpyridylformamidine ligand


Organic chemistry
10. Synthesis and characterization of MCM-41@L-arginine@Pd(0) and its excellent catalytic activity as recyclable heterogeneous catalyst for Suzuki-Miyaura cross-coupling reaction

Arash Ghorbani-Choghamarani; Somayeh Nazarzadeh; Elham Tahanpesar

Volume 7, Issue 4. pp. 352-471, Serial No. 25 , Autumn 2019, , Pages 368-379

http://dx.doi.org/10.30473/icc.2019.41086.1454

Abstract
  MCM-41@L-Arg@Pd(0) has been prepared by some consequence reactions. This nano structural material has been characterized via different technique including: XRD, TGA, BET, EDS, X-Ray maps, SEM, ICP-OES and FT-IR analysis. The synthesis of a variety of biphenyl compounds has been achieved successfully ...  Read More

Synthesis and characterization of MCM-41@L-arginine@Pd(0) and its excellent catalytic activity as recyclable heterogeneous catalyst for Suzuki-Miyaura cross-coupling reaction


Organic chemistry
11. A computational molecular approach on chitosan vehicle for metformin

Mahmoud Mirzaei; Oguz Gulseren; Elham Jafari; Mehdi Aramideh

Volume 7, Issue 4. pp. 352-471, Serial No. 25 , Autumn 2019, , Pages 380-389

http://dx.doi.org/10.30473/icc.2019.43014.1490

Abstract
  Density functional theory (DFT) calculations have been performed to study properties of chitosan (Chit) as a possible vehicle for carrying metformin (Met) drug. To this aim, the singular molecules of Met and Chit have been first optimized and sixteen possible bimolecular complexes have been subsequently ...  Read More

A computational molecular approach on chitosan vehicle for metformin


Organic chemistry
12. Informatics aided QSRR study of retention index of some volatile compounds

Abbas Farmany

Volume 7, Issue 3, pp. 242-351, Serial No. 24 , Summer 2019, , Pages 242-247

http://dx.doi.org/10.30473/icc.2019.43433.1500

Abstract
  In the present work, an artificial neural network (ANN) model was used to study the quantitative structure retention relationship (QSRR) of retention index (RI) of some volatile compounds in natural cocoa and conched chocolate powder. Molecular structural descriptors are selected using genetic algorithm ...  Read More

Informatics aided QSRR study of retention index of some volatile compounds


Organic chemistry
13. Modeling and interactions analysis of the novel antagonist agent flibanserin with 5-hydroxytryptamine 2A (5-HT2A) serotonin receptor as a HSDD treatment in premenopausal women

Mehdi Nabati

Volume 7, Issue 3, pp. 242-351, Serial No. 24 , Summer 2019, , Pages 324-334

http://dx.doi.org/10.30473/icc.2019.42605.1484

Abstract
  Flibanserin is a novel antagonist small molecule to treat the hypoactive sexual desire disorder (HSDD) in the premenopausal women. The present article is related to the structural and electronic properties study and docking analysis of the title compound with 5-hydroxytryptamine 2A (5-HT2A) serotonin ...  Read More

Modeling and interactions analysis of the novel antagonist agent flibanserin with 5-hydroxytryptamine 2A (5-HT2A) serotonin receptor as a HSDD treatment in premenopausal women


Organic chemistry
14. Multicomponent reaction for the synthesis of 2,3-dihydroquinazolin-4(1H)-ones using isatoic anhydride, aldehydes and NH4OAc under Solvent-free conditions

Asadollah Hassankhani

Volume 7, Issue 3, pp. 242-351, Serial No. 24 , Summer 2019, , Pages 248-256

http://dx.doi.org/10.30473/icc.2018.42489.1483

Abstract
  Quinazolinone derivatives are nowadays well recognized as valuable scaffold in drug discovery. In this manuscript an improved multicomponent process for the chemical synthesis of 2,3-dihydroquinazolin-4(1H)-one derivatives is described. Isatoic anhydride and aromatic aldehydes with ammonium acetate have ...  Read More

Multicomponent reaction for the synthesis of 2,3-dihydroquinazolin-4(1H)-ones using isatoic anhydride, aldehydes and NH4OAc under Solvent-free conditions


Organic chemistry
15. A simplified green approach for synthesis of arylquinoxalines under solvent-free clay-catalysed conditions

Jabbar Khalafy; Shadi Dilmaghani; Nasser Etivand; Ahmad Poursattar Marjani

Volume 7, Issue 3, pp. 242-351, Serial No. 24 , Summer 2019, , Pages 283-293

http://dx.doi.org/10.30473/icc.2018.40579.1443

Abstract
  A friendly benign, green, rapid and facile strategy for synthesis a series of arylquinoxalines was achieved by condensation of aromatic 1,2-diamines with arylglyoxals under clay-catalyzed as an inexpensive and eco-friendly catalyst using grindstone chemistry. Significant decreases in reaction times and ...  Read More

A simplified green approach for synthesis of arylquinoxalines under solvent-free clay-catalysed conditions


Organic chemistry
16. N1,N1,N2,N2-Tetramethyl-N1,N2-bis(sulfo)ethane-1,2-diaminium chloride as a highly efficient catalyst for synthesis of some nitrogen- and oxygen-containing heterocyclic compounds

Maryam Dashtizadeh; Maryam Khalili; Fatemeh Reghbat; Eshagh Abdi; Zahra Bahadori; Zahra Sadripour; Abdolkarim Zare; Khadijeh Didehban; Seyed Sajad Sajadikhah

Volume 7, Issue 3, pp. 242-351, Serial No. 24 , Summer 2019, , Pages 257-270

http://dx.doi.org/10.30473/icc.2018.40557.1441

Abstract
  In this research, a Brønsted acidic ionic liquid namely N1,N1,N2,N2-tetramethyl-N1,N2-bis(sulfo)ethane-1,2-diaminium chloride {[TMBSED][Cl]2} was employed as a highly efficient catalyst for the solvent-free production of some nitrogen- and oxygen-containing heterocyclic compounds including: (i) ...  Read More

N1,N1,N2,N2-Tetramethyl-N1,N2-bis(sulfo)ethane-1,2-diaminium chloride as a highly efficient catalyst for synthesis of some nitrogen- and oxygen-containing heterocyclic compounds


Organic chemistry
17. The use of topological indices to predict thermodynamic properties of amino acids derivatives

Afsaneh Safari; Fatemeh Shafiei

Volume 7, Issue 3, pp. 242-351, Serial No. 24 , Summer 2019, , Pages 310-323

http://dx.doi.org/10.30473/icc.2018.5106

Abstract
  In the present investigation the applicability of various topological indices are tested for the QSPR study on 80 amino acids derivatives. Relationship between the Randic' (1X), Balaban (J), Szeged (Sz), Harary (H), Wiener (W), Hyper-Wiener (WW) and Wiener Polarity (WP) indices to the thermodynamic Properties ...  Read More

The use of topological indices to predict thermodynamic properties of amino acids derivatives


Organic chemistry
18. 4-Aryl-2, 6-di(pyren-1-yl)pyridines: A facile procedure for synthesis and studying of fluorescence properties

Mohammad Reza Asaadi; Hosein Behmadi; Abdolhossein Massoudi; Mohammad Shaker

Volume 7, Issue 3, pp. 242-351, Serial No. 24 , Summer 2019, , Pages 302-309

http://dx.doi.org/10.30473/icc.2018.40457.1439

Abstract
  Pyrene and its derivatives exhibit thermal stability, high extinction coefficients, excimer formation, high photoluminescence, long fluorescence lifetime, fluorophoric properties and enhanced charge carrier mobility which make them find applications in optoelectronic area and are useful as large planar ...  Read More

4-Aryl-2, 6-di(pyren-1-yl)pyridines: A facile procedure for synthesis and studying of fluorescence properties


Organic chemistry
19. QSAR models to predict physico-chemical Properties of some barbiturate derivatives using molecular descriptors and genetic algorithm- multiple linear regressions

Fatemeh Shafiei; Elham Esmaeili

Volume 7, Issue 2, pp. 125-241, Serial No. 23 , Spring 2019, , Pages 170-179

http://dx.doi.org/10.30473/icc.2018.5113

Abstract
  In this study the relationship between choosing appropriate descriptors by genetic algorithm to the Polarizability (POL), Molar Refractivity (MR) and Octanol/water Partition Coefficient (LogP) of barbiturates is studied. The chemical structures of the molecules were optimized using ab initio 6-31G basis ...  Read More

QSAR models to predict physico-chemical Properties of some barbiturate derivatives using molecular descriptors and genetic algorithm- multiple linear regressions


Organic chemistry
20. An efficient facile and one-pot synthesis of 2-arylsubstituted benzimidazole derivatives using 1-methyl-3-(2-oxyethyl)-1H-imidazol-3-ium-borate sulfonic acid as a recyclable and highly efficient ionic liquid catalyst at green condition

Sami Sajjadifar; Issa Amini; Hadi Jabbari; Omidali Pouralimardan; Mohammad Hossein Fekri; Kaushik Pal

Volume 7, Issue 2, pp. 125-241, Serial No. 23 , Spring 2019, , Pages 191-199

http://dx.doi.org/10.30473/icc.2018.41600.1465

Abstract
  1-Methyl-3-(2-oxyethyl)-1H-Imidazol-3-ium-Borate Sulfonic Acid ([MOEI]-BSA) was easily prepared and used as a new and highly efficient solid acid catalyst for the synthesis of benzimidazole derivatives with high isolated yields. Various substituted benzimidazoles were synthesized by a combination of ...  Read More

An efficient facile and one-pot synthesis of 2-arylsubstituted benzimidazole derivatives using 1-methyl-3-(2-oxyethyl)-1H-imidazol-3-ium-borate sulfonic acid as a recyclable and highly efficient ionic liquid catalyst at green condition


Organic chemistry
21. Co(III)@Fe3O4@SiO2 salen complex as a highly selective and recoverable magnetic nanocatalyst for the oxidation of sulfides and benzylic alcohols

Ali Allahresani; Mohammad ali Nasseri; Alireza Nakhaei1 Nakhaei; Saeid Aghajani

Volume 7, Issue 2, pp. 125-241, Serial No. 23 , Spring 2019, , Pages 153-169

http://dx.doi.org/10.30473/icc.2018.5105

Abstract
  In this study, Co (III) salen complex was synthesized and immobilized onto the surface of Fe3O4@SiO2 magnetic nanoparticle. The heterogeneous nanocatalyst was characterized by different techniques including X-ray diffraction (XRD), Fourier transform infrared spectra (FT-IR), thermogravimetric analysis ...  Read More

Co(III)@Fe3O4@SiO2 salen complex as a highly selective and recoverable magnetic nanocatalyst for the oxidation of sulfides and benzylic alcohols


Organic chemistry
22. Turmeric extract as a biocompatible inhibitor of mild steel corrosion in 3.5% NaCl solution

Milad Edraki; Issa Mousazadeh Moghadam; Mohammad Banimahd Keivani; Mohammad Hossein Fekri

Volume 7, Issue 2, pp. 125-241, Serial No. 23 , Spring 2019, , Pages 228-241

http://dx.doi.org/10.30473/icc.2018.42617.1486

Abstract
  Corrosion inhibitory impacts of turmeric with concentrations of 200-800 ppm on the electrochemical behavior of mild steel were studied in the medium of NaCl 3.5% using several techniques such as electrochemical impedance spectroscopy (EIS) and polarization. Scanning electron microscopy (SEM) was used ...  Read More

Turmeric extract as a biocompatible inhibitor of mild steel corrosion in 3.5% NaCl solution


Organic chemistry
23. A clean and efficient synthesis of spiro[4H-pyran-oxindole] derivatives catalyzed by egg shell

leila Youseftabar-Miri

Volume 7, Issue 2, pp. 125-241, Serial No. 23 , Spring 2019, , Pages 142-152

http://dx.doi.org/10.30473/icc.2019.4664

Abstract
  Egg shell has been utilized as a natural, green, reusable and eco-friendly reagent for the synthesis of spiro[4H-pyran-oxindole] derivatives by one-pot multicomponent reaction of isatins, 1,3-diketones, and malononitrile/ ethyl cyanoacetate. Good functional group tolerance and broad scope of usable substrates ...  Read More

A clean and efficient synthesis of spiro[4H-pyran-oxindole] derivatives catalyzed by egg shell


Organic chemistry
24. One-pot synthesis of ferrocene-containing 1,3,4-oxadiazole derivatives from N-isocyaniminotriphenylphosphorane (Ph3PNNC), cyclic ketones and ferrocene carboxylic acid

Mona Ashtary; Ali Ramazani; Morteza Rouhani

Volume 7, Issue 1, pp. 1-124, Serial No. 22 , Winter 2019, , Pages 117-124

http://dx.doi.org/10.30473/icc.2019.4543

Abstract
  Reactions of N-isocyaniminotriphenylphosphorane with a cyclic ketone in the presence of ferrocene carboxylic acid proceeded smoothly at room temperature and in neutral conditions to afford ferrocene-containing 1,3,4-oxadiazole derivatives in high yields. The reaction proceeded smoothly and cleanly under ...  Read More

One-pot synthesis of ferrocene-containing 1,3,4-oxadiazole derivatives from N-isocyaniminotriphenylphosphorane (Ph3PNNC), cyclic ketones and ferrocene carboxylic acid


Organic chemistry
25. Synthesis, characterization and spectroscopic properties of new azo dyes derived from aniline derivatives based on acetylacetone and azo-metal (II) complexes and singular value decomposition (SVD) investigation

Nader Noroozi Pesyan; Vali Gholsanamloo; Maryam Moradi Par; Hamid Rashidnejad; Ali Gharib; Kamelia Nejati

Volume 7, Issue 1, pp. 1-124, Serial No. 22 , Winter 2019, , Pages 1-19

http://dx.doi.org/10.30473/icc.2019.3951

Abstract
  Four new azo-dyes, 3-phenyl azopentane-2,4-dion (LA), 3-(4-nitro phenyl azo)-pentane-2,4-dion (LP), 3-(2-nitro phenyl azo)-pentane-2,4-dion (LO) and 4-(1-acetyle-2-oxo-propyl azo)-benzene sulfonate sodium (LS), were synthesized from, aniline, 4-nitroaniline, 2-nitroaniline and sulfanilic acid with acetylacetone, ...  Read More

Synthesis, characterization and spectroscopic properties of new azo dyes derived from aniline derivatives based on acetylacetone and azo-metal (II) complexes and singular value decomposition (SVD) investigation