Selectfluor [1-(chloro methyl) -4-flouro -1,4-di azonia bicyclo[2,2,2] octane bis (tetraflouro-borate)] catalyzed the preparation of quinoxaline and 2,3-dihydo pyrazine derivatives through one -pot condensation of 1,2-di amines with 1,2-di carbonyls in solvent and under solvent- free conditions. This catalyst is commercially available, inexpensive, reusable, stable to air and moisture, and relatively non-toxic. Furthermore, very short reaction times, high yields of products, mild reaction conditions, absence of solvent, and easy work-up are other considerable advantages of these procedures. Also, a resonable mechanism has been proposed for the current reaction. The chemical structure and purity of the products were characterized by 1H NMR and IR spectroscopy.