Document Type: Original Research Article

Authors

1 Department of Chemistry, Payame Noor University (PNU), Iran

2 Department of Industrial Engineering, Payame Noor University, P.O. BOX 19395-4697 Tehran, Iran

Abstract

In this paper we report the synthesis and characterization of two new binuclear Cd(II) macrocyclic Schiff base complexes [CdL23pydfp(NO3)], (1), and [CdL33pydfp(NO3)], (2). [1+1] cyclocondensation of L23py = N-(2-pyridylmethyl)-N-(3-aminpropyl)-1,3-diaminoethane and L33py = N-(3-pyridylmethyl)-N-(3-aminpropyl)-1,3-diaminopropane and 2,6-diformyl-4-methylphenol, dfp, in the presence of Cd(NO3)2.4H2O in equimolar ratios gave two new macrocylclic complexes. Resulting complexes were characterized by NMR, IR, mass spectroscopy and elemental analysis. Spectroscopy studying results show in spite the nitrogen and oxygen atoms of macrocyclic ligand with N4O donor set, one nitrate molecule (with two donor oxygen atoms) is coordinated to the Cd(II) center in each complex. So, the cadmium center is seven coordinated.

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[1] I. Sheikhshoaiea, M. Sheikhshoaie, S. Ramezanpour, Chem. Method., 2018, 2, 103-113.

[2] A. Strancar, P. Raspor, H. Schwinn, R. Schutz and D. Josic J. Chromatogr., A, 1994, 658, 457-463.

[3] P.C. Tsai and W. H. Ding J. Chromatogr. A., 2004, 1027, 103-106.

[4] C. Vogt and K. Heinig J. Anal. Chem., 1999, 363, 612-618.

[5] J.J. Morelli and G. Szajer J. Surfactants Detergents., 2000, 3, 359-368.

[6] J.J. Morelli and G. Szajer J. Surfactants Detergents., 2001, 4, 75-84.

[7] M. Barco, C. Planas, O. Palacios, F. Ventura, J. Rivera and J. Caixach Anal. Chem., 2003, 75, 5129-5136.

[8] R. Lander, M. Winters, F. Meacle, B. Buckland and A. Lee Biotechnol. Bioeng., 2002, 79, 776-781.

[9] Lorenzo H. Chen, Colleen E. Price, Aaron Goerke, Ann L. Lee and Pete A. De Phillips J. Pharmaceutical and Biomedical Analysis., 2006, 40, 964-968.

[10] A.N. Anthemidis and K.I.G. Ioannou Talanta., 2009, 80, 413-418.

[11] A.N. Anthemidis and M. Miro Appl. Spectrosc. Rev., 2009, 44, 140-149.

[12] F. Pena-Pereira, I. Lavilla and C. Bendicho Spectrochim. Acta B., 2009, 64, 1-7.

[13] M. Miro, J.M. Estela and V. Cerda Curr. Anal. Chem., 2005, 1, 329-333.

[14] A.N. Anthemidis and I.S.I. Adam Anal. Chim. Acta., 2009, 632, 216-221.

[15] M. Rezaee, Y. Assadi, M.R. MilaniHosseini, E. Aghaee, F. Ahmadi and S. Berijani J. Chromatogr. A., 2006, 1116, 1-8.

[16] A. Bidari, P. Hemmatkhah, S. Jafarvand, M.R.M. Hosseini and Y. Assadi Microchim. Acta., 2008, 163, 243-248.

[17] W.C. Tsai and S.D. Huang J. Chromatogr. A., 2009, 1216, 5171-5176.

[18] M.A. Farajzadeh, M. Bahrama and J.A. Jonsson Anal. Chim. Acta., 2007, 591, 69-75.

[19] E.Z. Jahromi, A. Bidari, Y. Assadi, M.R.M. Hosseini and M.R. Jamali Anal. Chim.Acta., 2007, 585, 305-308.

[20] M.A. Farajzadeh, M. Bahram, B.G. Mehr and J.A. Jonsson Talanta., 2008, 75, 832-838.

[21] N.Brianese, U.Casellato, S.Tamburini, P.Tomasin, P.A.Vigato Inorg. Chim. Acta., 1999, 293, 178-184.

[22] S. Salehzadeh, R. Golbedaghi, I.S. Tidmarsh, N.K. Al-Rasbi, H. Adams Polyhedron., 2008, 27, 3549-3554.

[23] R. Golbedaghi, S. Salehzadeh, H. Keypour, A.G. Blackman Polyhedron., 2010, 29, 850-856.

[24] R. Golbedaghi, M. Rezaeivala, L. Albeheshti J. Mol. Struct., 2014, 1076, 673-677.

[25] R.Golbedaghi, S.Salehzadeh,H. Keypour, I.S. Tidmarsh, L. Sorace, H. Adams, M.D Ward Polyhedron., 2009, 28, 162-168.

[26] (a) J.S. Casas, M.V. Castano, M.S. Garcia-Tasende, I. Martinez-Santamarta, J. Sordo, E.E. Castellano, J. Zuckerman-Schpector J. Chem. Res., (S), 1992, 324, 564-569; (b) J.S. Casas, M.V. Castano, M.S. Garcia- Tasende, I. Martinez-Santamarta, J. Sordo, E.E. Castellano, J. Zuckerman-Schpector  J. Chem. Res., (M), 1992, 2626, 432-438

[27] O. Zerbe, D.L. Pountney, W.V. Philipsborn, M. Vasak J. Am. Chem. Soc., 1994, 116, 377.

[28] D.C. Bebout, S.W. Stokes, R.J. Butcher Inorg. Chem., 1999, 38, 1126-1134.

[29] L. Valencia, H. Adams, R. Bastida, D.E. Fenton, A. Macias Inorg. Chem. Acta., 2001, 317, 45-51.

[30] X. Liang, J.A. Parkinson, S. Parsons, M. Weishaupl, P.J. Sadler Inorg. Chem., 2002, 41, 4539-4543.

[31] M.J. Frisch, G.W. Trucks, H.B. Schlegel, G.E. Scuseria, M.A. Robb, J.R Cheeseman, J.A. Montgomery Jr., T. Vreven, K.N. Kudin, J.C. Burant, J.M. Millam, S.S. Iyengar, J. Tomasi, V. Barone, B. Mennucci, M. Cossi, G. Scalmani, N. Rega, G.A. Petersson, H. Nakatsuji, M. Hada, M. Ehara, K. Toyota, R. Fukuda, J. Hasegawa, M. Ishida, T. Nakajima, Y. Honda, O. Kitao, H. Nakai, M. Klene, X.  Li, J.E. Knox, H.P. Hratchian, J.B. Cross, C. Adamo, J. Jaramillo, R. Gomperts, R.E. Stratmann, O. Yazyev, A.J. Austin, R. Cammi, C. Pomelli, J.W. Ochterski, P.Y. Ayala, K. Morokuma, G.A. Voth, P. Salvador, J.J. Dannenberg, V.G. Zakrzewski, S. Dapprich, A.D.  Daniels, M.C. Strain, O. Farkas, D.K. Malick, A.D. Rabuck, K. Raghavachari, J.B. Foresman, J.V. Ortiz, Q. Cui, A.G. Baboul, S. Clifford, J. Cioslowski, B.B. Stefanov, G. Liu, A.

Liashenko, P. Piskorz, I.  Komaromi, R.L. Martin, D.J. Fox, T. Keith, M.A. Al- Laham, C.Y. Peng, A. Nanayakkara,   M. Challacombe, P.M.W. Gill, B. Johnson, W. Chen, M.W. Wong, C.  Gonzalez, J.A.  Pople, Gaussian 03, Revision B.01, Gaussian, Inc., Pittsburgh PA, 2003.

[32] C. Lee, W. Yang, R.G. Parr Phys. Rev. B., 1998, 37, 785-793.

[33] W.J. Hehre, R. Ditchfield, J.A. Pople J. Chem. Phys., 1972, 56, 2257-2264.

[34] R. Golbedaghi, S. Salehzadeh, H.R. Khavasi, A.G. Blackman Polyhedron., 2014, 68, 151-158.

[35] N. Brianese, U. Casellato, S. Tamburini, P. Tomasin, P.A. Vigato Inorg. Chim. Acta., 1999, 293, 178-183.

[36] S.J. Archibald, A.J. Blake, S. Parsons, M. Schröder, R.E.P. Winpenny J. Chem. Soc., Dalton Trans., 1997, 173-179.

[37] M.G.B. Drew, O.W. Howarth, G.G. Morgan, J. Nelson, J. Chem. Soc., Dalton Trans., 1994, 3149-3156.

[38] M.G.B. Drew, O.W. Howarth, N. Martin, G.C. Morgan, J. Nelson J. Chem. Soc., Dalton Trans., 2000, 1275-1283.

[39] J.R. Gispert, Omega., 2000, 46, 324-328.

[40] R. Golbedaghi. E. Alavipour Iranian Chemical Communication., 2016, 4, 133-141.

[41] N. Samadi, R. Ansari, B. Khodavirdilo, Asian Journal of Green Chemistry., 2018, 2, 338-363.

[42] A. Mirzaie, Journal of Medicinal and Chemical Sciences., 2018, 1, 5-8.