(Carboxy-3-oxopropylamino)-3-propylsilylcellulose as a novel organocatalyst for the synthesis of coumarin derivatives under solvent-free conditions

Salimi, Mehri

Document Type : Original Research Article

Author

Mehri Salimi

Department of Chemistry, College of Sciences, University of Birjand, P. O. Box 97175-615, Birjand, Iran

Abstract

In this research, (Carboxy-3-oxopropylamino)-3-propylsilylcellulose (COPAPSC) as an organocatalyst, has been synthesized by grafting of succinic anhydride on the NH2-modified cellulose (cellulose functionalized with 3- aminopropyltriethoxysilane). The –CO2H group-functionalized cellulose (COPAPSC) is used as a catalyst for the synthesis of coumarin derivatives from the reaction of phenolic substrate and β- Keto-esters under solvent-free conditions. The results showed that the yield of products is between 85-94%. The advantages of this reaction include simple work-up, short reaction time, excellent yields as well as easily separation of catalyst. The catalyst can be reused several times in subsequent reactions without any decreasing in the catalyst reactivity.

Graphical Abstract

Keywords

Main Subjects

Organic chemistry

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Iranian chemical communication

(Carboxy-3-oxopropylamino)-3-propylsilylcellulose as a novel organocatalyst for the synthesis of coumarin derivatives under solvent-free conditions

References

References

Volume 4, Issue 3, pp. 236-358, Serial No. 12
July 2016
Pages 295-308

(Carboxy-3-oxopropylamino)-3-propylsilylcellulose as a novel organocatalyst for the synthesis of coumarin derivatives under solvent-free conditions

References

References

Volume 4, Issue 3, pp. 236-358, Serial No. 12July 2016Pages 295-308

Volume 4, Issue 3, pp. 236-358, Serial No. 12
July 2016
Pages 295-308