Synthesis, characterization and selective oxidation using a new copper (II) Schiff base complex derived from Alanine and 4-chloro3- formyl coumarin

Ebrahimpour, Malihe; Bagherzade, Ghodsieh; Sajadi, Ali Akbar; Khani, Rouhollah

Document Type : Original Research Article

Authors

¹ Department of Chemistry, Faculty of Sciences, University of Birjand

² Sharif University of Technology

Abstract

A novel Schiff-base ligand (L: 2-[(4-chloro-2-oxo-2H-chromen-3-ylmethylene)-amino] propionic acid) was prepared from the reaction of 4-chloro3-formylcoumarin and alanine amino acid. Copper (II) complex was synthesized from the reaction of the ligand with Cu (OAc)2. H2O in ethanol. The ligand and its metal complex were characterized by elemental analysis (CHN), ICP, thermal analysis (TGA), Fourier transform infrared spectroscopy (FT-IR), 1HNMR, and 13C NMR techniques. The complex was found to be an efficient catalyst and reusable in the selective oxidation of sulfides to the corresponding sulfoxides without the formation of any sulfone using the green oxidant, H2O2, at room temperature and under solvent-free conditions.

Graphical Abstract

Keywords

Main Subjects

Organic chemistry

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Iranian chemical communication

Synthesis, characterization and selective oxidation using a new copper (II) Schiff base complex derived from Alanine and 4-chloro3- formyl coumarin

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References

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Volume 6, Issue 3, pp. 218-324, Serial No. 20
July 2018
Pages 228-241

Synthesis, characterization and selective oxidation using a new copper (II) Schiff base complex derived from Alanine and 4-chloro3- formyl coumarin

References

References

[6] M. Nath, P.K. Saini, Dalton Trans., 2011, 40, 7077-7121.

[7] Z. Cimerman, S. Miljanić N. Galić, Croat.Chem. Acta., 2000, 73, 81-95.

[13] Gh. Grivani, G. Bruno, H. Amiri Rudbari, A. Dehno Khalaji, P. Pourteimouri, Inorg. Chem. Commun., 2012, 18, 15-20.

[14] O. Pouralimardan, A.C. Chamayou, C. Janiak, H. Hosseini-Monfared, Inorg Chim Acta., 2007, 360, 1599-1608.

[20] V. Conte, F. Fabbianesi, B. Floris, P. Galloni, D. Sordi, I.W. Arends, M. Bonchio, D. Rehder, D. Bogdal, Pure. Appl. Chem., 2009, 81, 1265-1277.

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Volume 6, Issue 3, pp. 218-324, Serial No. 20July 2018Pages 228-241

Volume 6, Issue 3, pp. 218-324, Serial No. 20
July 2018
Pages 228-241