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Synthesis, characterization, antibacterial activity and molecular modeling studies of Ni(II) and Zn(II) complexes with phenylpyridylformamidine ligand

Document Type : Original Research Article

Authors

1 Department of Chemistry, Payame Noor University of Ilam, Iran

2 bIlam Petrochemical, Company (ILPC), P. O. Box 6931994749 ,Ilam, Iran

Abstract

The Ni(II) and Zn(II) complexes with phenylpyridylformamidine (PhPyF) ligand, [Ni(PhPyF)Cl2] and [Zn(PhPyF)Cl2], have been prepared and investigated using different chemical techniques such as elemental analysis, molar conductance, FT-IR, UV-vis spectra and magnetic moment. The obtained chemical analysis data showed the formation of 1:1 (metal: ligand) ratio. The square planar and tetrahedral geometry for NiL and ZnL respctively, were suggested on the basis of magnetic moment, spectral data and molecular modeling studies. The free ligand and its metal complexes have been tested in vitro against a number of bacteria (Gram-negative and Gram- positive) in order to assess their antibacterial activities.
Keywords: Ni (II) and Zn(II) complexes, Phenylpyridylformamidine, molecular modeling.

Graphical Abstract

Synthesis, characterization, antibacterial activity and molecular modeling studies of Ni(II) and Zn(II) complexes with phenylpyridylformamidine ligand

Keywords

Main Subjects

References
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Iranian chemical communication
Volume 7, Issue 4. pp. 230-306, Serial No. 25
October 2019
Pages 264-271
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