Reusable Silica supported Perchloric acid and potassium bisulphate as green catalysts for thiocyanation of aromatic compounds under solvent free conditions

Kamatala, Chinna Rajanna; Y., Hemanth Sriram; Mukka, Satish Kumar; Marri, Venkateswarlu; Fatima, Touheeth; Mukka, Sai Sudhakar; R., Madhusudan Raju

Document Type : Original Research Article

Authors

¹ Department of Chemistry, Osmania University, Hyderabad (T.S)-500007 India

² Department of Chemistry Osmania University Hyederabad -(T.S) 500007 India

³ Department of Chemistry Osmania University Hyderabad-(T.S) India

⁴ Department of Chemistry Osmania Univerity Hyderabad-(T.S) India

⁵ Department of Chemistry Osmania University Hyderabad -(T.S) India

⁶ School of Chemistry BITS, Pilani, Hyderabad

⁷ Department of Chemistry Osmania University Hyderabad-T.S India

Abstract

Reusable silica supported perchloric acid and potassium bisulphate have been prepared and explored as green catalysts for thiocyanation of aromatic compounds under conventional and solvent free microwave assisted conditions. The microwave assisted protocol exhibited remarkable rate accelerations and offered selective thiocyanation of aromatic and hetero aromatic compounds in good yields. Reaction times observed in conventional methods range of 2.0 to 6.0 hours, which reduced to only few minutes (1 to 3 min) in microwave assisted reactions. The developed protocols are also promising and comparable with the existing procedures. Prepared catalysts could be easily recycled for five time with a reproducible efficiency.

Graphical Abstract

Keywords

Main Subjects

Organic chemistry

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Iranian chemical communication

Reusable Silica supported Perchloric acid and potassium bisulphate as green catalysts for thiocyanation of aromatic compounds under solvent free conditions

References

References

Volume 5, Issue 3, pp. 237-363, Serial No. 16
July 2017
Pages 352-363

Reusable Silica supported Perchloric acid and potassium bisulphate as green catalysts for thiocyanation of aromatic compounds under solvent free conditions

References

References

Volume 5, Issue 3, pp. 237-363, Serial No. 16July 2017Pages 352-363

Volume 5, Issue 3, pp. 237-363, Serial No. 16
July 2017
Pages 352-363