Synthesis, biological and molecular modeling studies of macrocyclic complexes of trivalent metal ions

Sangwan, Vikas; Singh, Dharam Pal

Document Type : Original Research Article

Authors

Vikas Sangwan ¹
Dharam Pal Singh ²

¹ nit kurukshetra

² nit,kurukshetra

Abstract

The macrocyclic complexes of biological importance with power transition metals are synthesized by template methodology leading to the formation of the complex [MLX] X2; where L is macrocyclic ligand derived from 3,4-diaminotoluene, 2,4-thiazolidinedione, M=Cr (III) and Fe(III) X is Cl-, CH3COO- or NO3_.Characterisation of these complexes are through with the assistance of elemental analyses(CHN), molar conductance measurements, magnetic susceptiblities measurements and infrared spectral studies. Molecular modelling was done by using Avagadro 1.01 progarm and optimised geometry in which energy calculations of macrocyclic complexes were determined. Synthesised complexes were also screened for their biological activities such as antimicrobial,antifungal and antioxidant activities.

Graphical Abstract

Keywords

Main Subjects

Inorganic chemistry

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Iranian chemical communication

Synthesis, biological and molecular modeling studies of macrocyclic complexes of trivalent metal ions

References

References

Volume 5, Issue 3, pp. 237-363, Serial No. 16
July 2017
Pages 345-351

Synthesis, biological and molecular modeling studies of macrocyclic complexes of trivalent metal ions

References

References

Volume 5, Issue 3, pp. 237-363, Serial No. 16July 2017Pages 345-351

Volume 5, Issue 3, pp. 237-363, Serial No. 16
July 2017
Pages 345-351