Silica bonded n-propyl-1,3,5-triazine-2,4,6-triamine as a basic catalyst for synthesis of arylmethylenemalononitrile and pyran annulated heterocyclic compounds

Davarpanah, Jamal; Zafarpour, Afzal; Tayebi, Behrooz

Document Type : Original Research Article

Authors

¹ Production Technology Research Institute (ACECR), Ahwaz, Iran.

² Chemistry Department, Omidiyeh Branch of Islamic Azad University, Omidiyeh, Iran

Abstract

In the present research, silica bonded n-propyl-1,3,5-triazine-2,4,6-triamine (SPTT) was synthesized by direct incorporation of chloropropyl groups through co-condensation of tetraethyl orthosilicate (TEOS) and 3-chloropropyl trimethoxysilane (CPTMS) and subsequent grafting the melamine onto the propyl groups via simple nucleophilic substitution reaction. The catalyst has been characterized by fourier transform infrared spectroscopy (FT-IR) and thermogravimetric analysis (TGA). The catalytic activity of catalyst was probed through synthesis of arylmethylenemalononitrile and pyran annulated heterocyclic compounds.The catalytic activity of catalyst was probed through synthesis of arylmethylenemalononitrile and pyran annulated heterocyclic compounds.The catalytic activity of catalyst was probed through synthesis of arylmethylenemalononitrile and pyran annulated heterocyclic compounds.

Graphical Abstract

Keywords

Main Subjects

Organic chemistry

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Iranian chemical communication

Silica bonded n-propyl-1,3,5-triazine-2,4,6-triamine as a basic catalyst for synthesis of arylmethylenemalononitrile and pyran annulated heterocyclic compounds

References

References

Volume 5, Issue 4, pp. 364-493, Serial No. 17
October 2017
Pages 471-483

Silica bonded n-propyl-1,3,5-triazine-2,4,6-triamine as a basic catalyst for synthesis of arylmethylenemalononitrile and pyran annulated heterocyclic compounds

References

References

Volume 5, Issue 4, pp. 364-493, Serial No. 17October 2017Pages 471-483

Volume 5, Issue 4, pp. 364-493, Serial No. 17
October 2017
Pages 471-483