Determination of trace amounts of chromium ions in water and food samples using ligand-less solid phase extraction-based modified nano-boehmite(AlOOH)

Rezaiati, Mohammad; Salimi, Farhad; Karami, Changiz

Document Type : Original Research Article

Authors

¹ Azad university

² Azad university of kermanshah

³ Shahid bahonar university

Abstract

Chromium is one of the hazardous pollutants in industrial effluents. In this study, a new nano-boehmite modiﬁed with sodium dodecyl sulphate is developed for preconcentration trace amounts of chromium ions as a prior step to its determination by ﬂame atomic absorption spectrometry. We investigated the effect of various parameters on the recovery of the analyte ions, including pH of sample solution, amount of sorbent, sample volume on extraction efficiency of the chromium ions. Under the best experimental conditions, the calibration curve was linear in the range of 1.0 -700.0 ng.mL-1 of chromium with R2 = 0.997. Detection limit was 0.6 ng.mL-1 in the original solution (3Sb/m) and the relative standard deviation for seven replicate determination of 0.5 µg.mL-1 chromium was ±2.4%. The developed method was successfully applied to the extraction and determination of chromium in water and food samples with satisfactory results.

Graphical Abstract

Keywords

Main Subjects

Analytical chemistry

References

[1] S. Sahan, S. Sacmac, S. Kartal, M. Sacmac, U. Sahin, A. Ulgen, Talanta, 2014, 120, 391–397.

[2] R. Dobrowolski, I. Pawlowska-Kapusta, J. Dobrzynska, Food Chemistry, 2012, 132, 597–602.

[3] Q. Chang, Sh. Song, Y. Wang, J. Li, J. Ma, Anal. Methods., 2012, 4, 1110-1116.

[4] O. Murat-Kalfa, O. Yalcinkay, A. Rehber-Türker, J. Hazard. Mater., 2009, 166, 455–461.

[5] V.A. Lemos, G.T. David, Microhem. J., 2010, 94, 42–47.

[6] M.G. Pereira, M.A.Z. Arruda, Microchim. Acta., 2003, 141, 115–131.

[7] S. Jafarvand, A. Bidari, P. Hemmatkhah, M.R.M. Hosseini, Y. Assadi, Anal. Letters., 2009, 42, 2214–2231.

[8] A.N. Tang, D.Q. Jiang, X.P. Yan, Anal. Chim. Acta., 2004, 507, 203–208.

[9] C.C. Nascentes, M.A.Z. Arruda, Talanta, 2003, 61, 759-768.

[10] H. Parham, N. Pourreza, N. Rahbar, J. Hazard. Mater., 2009, 163, 588–592.

[11] C. Araneda, C. Fonseca, J. Sapag, C. Basualto, M. Yazdani-Pedram, K. Kondo, E. Kamio, F. Valenzuela, Sep. Purif. Tech., 2008, 63, 517–523.

[12] E.L. Silva, P.S. Roldan, J. Hazard. Mater., 2009, 161, 142–147.

[13] S.Z. Mohammadi, D. Afzali, M.A. Taher, Y.M. Baghelani, Talanta, 2009, 80, 875–879.

[14] F. Sabermahani, M.A. Taher, H. Bahrami, S. Fozooni, J. Hazard. Mater., 2011, 185, 945–950.

[15] G. Yang, W. Fen, C. Lei, W. Xiao, H. Sun, J. Hazard. Mater., 2009, 162, 44–49.

[16] M. Faraji, Y. Yamini Sh. Shariati, J. Hazard. Mater., 2009, 166, 1383–1388.

[17] Sh. Shariati, Y. Yamini, M. Faraji, A. Saleh, Microchim. Acta., 2009, 165, 65–72.

[18] M. Amjadi, A. Samadi, J.L. Manzoori, Microchem. Acta., 2015, 182, 1627-1633.

[19] G. Fei, L. Meng-Meng, Y. Hui, Z. Bao-Xiang, J. Hazard. Mater., 2011, 211– 212, 366-372.

[20] M.E. Mahmoud, M.S. Abdelwahab, E.M. Fathallah, Chem. Eng. J., 2013, 223, 318-327.

[21] M. Abdolahifar, M. R. Zamani, E. Beiygie, H. Nekouei, J. Serb. Chem. Soc., 2014, 79, 1007–1017.

[22] A. Heidari, H. Younesi, Z. Mehraban, Chem. Eng. J., 2009, 153, 70–79.

[23] X. Zhao, N. Song, W. Zhou, Q. Jia, Cent. Eur. J. Chem., 2012, 10, 927-937.

[24] S. Samac1, S. Kartal, Y. Yilmaz, M. Samacy, C. Soykan, Chem. Eng. J., 2012, 181, 746-753.

[25] N. Rajesh, B. Deepthi, A. Subramaniam, J. Hazard. Mater., 2007, 144, 464-469.

[26] C. Duran, M. Soylak, V.N. Bulut, L. Elci , A. Gundogdu, H.B. Senturk, M. Tufekci, J. Chin. Chem. Soc., 2007, 54, 625-634.

Iranian chemical communication

Determination of trace amounts of chromium ions in water and food samples using ligand-less solid phase extraction-based modified nano-boehmite(AlOOH)

References

References

Volume 5, Issue 4, pp. 364-493, Serial No. 17
October 2017
Pages 397-406

Determination of trace amounts of chromium ions in water and food samples using ligand-less solid phase extraction-based modified nano-boehmite(AlOOH)

References

References

Volume 5, Issue 4, pp. 364-493, Serial No. 17October 2017Pages 397-406

Volume 5, Issue 4, pp. 364-493, Serial No. 17
October 2017
Pages 397-406