Application of the extended solvation theory to study the interaction of β-CD with interpolymer of PEO and PAA

Vasheghani Farahani, Bahman; Rezaei Behbahani, Golamreza; Shalbafan, Monir

Document Type : Original Research Article

Authors

¹ IMMAM KHOMEINI INTERNATHIONAL UNIVERSITY

² Imam Khomeini International University

Abstract

Thermodynamic study on the interaction of β-CD with poly ethylene oxide and poly acrylic acid was performed by isothermal titration calorimetry at 298K. when β-CD is added to the interpolymer complex, competition is created between host-guest and Hydrogen bond.
Enthalpy of interaction between the β-CD and interpolymer complex was calculated using the extended solvation theory. P=1 Shows that willingness of β-CD to interact with both polymers is identical. The positive values of and show that interpolymer complex are stabilized by β-CD . The process is both enthalpy and entropy-driven. The results show that this interaction is exothermic and increases the interpolymer complex stability.

Graphical Abstract

Keywords

Main Subjects

Physical chemistry

References

[1] N.J. Turro, Acad. Sci. USA., 2005, 102, 10766–10770.

[2] H. Dodziuk, Springer., 2002, 6, 47-63.

[3] F. Cramer, H. Hettler, Naturwissenschaften., 1967, 54, 625–32.

[4] J. Szejtli, Chem. Rev., 1998, 98, 1743–1754.

[5]H. Dodziuk, Wiley. Weinheim. Germany., 2006, 4, 65-92.

[6] J. Carrazana, B. Reija, P. RamosCabrer, W. Al-Soufi, M. Novo, J. Vázquez Tato, Supramol. Chem., 2004, 16, 549–559.

[7] J. Bordello, B. Reija, W. Al-Soufi, M. Novo, Chemphyschem., 2009, 10, 931–939.

[8] B. Reija, W. Al-Soufi, M. Novo, J. Vázquez Tato, J. Phys. Chem. B., 2005, 109, 1364–1370.

[9] C. Bohne, Spectrum., 2000, 13, 14–19.

[10] A. Harada, M. Kamachi, Nature., 1993, 364, 516-522.

[11] J. Lehn, Supramolecular Chemistry., 1995, 1-271.

[12] S.A. Nepogodiev, J.F. Stoddart, Chem. Rev., 1998, 98, 1959–1976.

[13] E. Alvarez Parrilla, P. Ramos Cabrer, W. Al-Soufi, F. Meijide del Río,E. A. Rodríguez Núñez, J.Vázquez Tato, Chem. Int. Ed. Engl., 2000, 39, 2856–2858.

[14] T. Ogoshi, A. Harada, Sensors., 2008, 8, 4961–4982.

[15] A. Hennig, H. Bakirci, W. M. Nau, Nat. Methods., 2007, 4, 629–632.

[16] R. Breslow, S. Belvedere, L. Gershell, D. Leung, Pure Appl. Chem., 2000, 72, 333–342.

[17] T. Loftsson, M.E. Brewster, J. Pharm. Sci., 1996, 85, 1017–1025.

[18] K. Uekama, F. Hirayama, T. Irie, Chem. Rev., 1998, 98, 2045–2076.

[19] F. Hirayama, K. Uekama, Adv. Drug Deliv.Rev., 1999, 36, 125–141.

[20] M. Lezcano, W. Al-Soufi, M. Novo, Rodríguez- E.Núñez, J. Vázquez Tato, J. Agric. FoodChem., 2010, 11, 173–188.

[21] H. Ritter, M. Tabatabai, Progr.J Polym. Sci., 2002, 27, 1713–1720.

[22] M.E. Davis, M.E. Brewster Nat, Rev. Drug Discov., 2004, 3, 1023–1035.

[23] P. Jadhav, B. Petkar, Y. Pore, A. Kulkarni, K. Burade, Carbohydr Polym., 2013, 98(2), 1317-25.

[24] B. Pose-Vilarnovo, C.R.T. Sanchez, M.B. Perez-Marcos, J.J. Torres- Labandeira, J. Therm. Anal. Calorim., 2002, 68, 657-662.

[25] T.T. Nielsen, V. Wintgens, K.L. Larsen, C. Amiel, J. Incl. Phenom. Macrocycl. Chem., 2009, 65, 341-348.

[26] E.A. Bekturov, L.A. Bimendina, J. Adv Polym Sci., 1981, 41, 99–148.

[27] E. Tsuchida K. Abe, J. Adv Polym Sci., 1982, 45, 1–119.

[28] M. Jiang, M. Li, H. XiangMand Zhou, J. Adv Polym Sci., 1999, 146, 121–196.

[29] Z.S. Nurkeeva, J.Polym Sci B., 2001, 43, 148–157.

[30] VV. Khutoryanskiy, G. Staikos, World Scientific, Singapore, 2009, 52, 46-70.

[31] G.H. Holdgate, W.H.J. Ward, Drug Discov., 2005, 10, 1543–1550

[32] A.A. Saboury, J. Iran. Chem. Soc., 2006, 3, 1–21.

[33] K. Bouchemal, Drug Discov., 2008, 13, 960–972.

[34] J. Courtois, J.F. Berret, Langmuir, 2010, 26, 11750–11758.

[35] F. Vial, Langmuir., 2009, 25, 7506–7513.

[36] M. Bellot, L. Bouteiller, Langmuir., 2008, 24, 14176–14182.

[37] K. Bouchemal, J. Colloid Interface Sci., 2009, 338, 169–176.

[38] K. Bouchemal, J Mol. Recognit., 2010, 22, 235–242.

[39] C. Roques, J. Control. Release., 2009, 138, 71–77.

[40] K. Bouchemal, J. Therm. Anal. Calorim., 2009, 98, 57–64.

[41] S. Daoud-Mahammed, Biomacromolecules., 2009, 10, 547–554.

[42] S. Daoud-MahammedCurr. Nanosci., 2010, 6, 1–12.

[43] M. Othman, J. Pharm., 2009, 379, 218–225.

[44] S. Sajeesh, J. Control. Release., 2010, 147, 377–384 .

[45] S. Mazzaferro, J. Pharm., 2011, 413, 171–180.

[46] V. Wintgens, Biomacromolecules., 2008, 9, 1434–1442.

[47] S.K. Osman, J.Polymer., 2011, 52, 4806–4812.

[48] F. Segura-Sanchez, J. Mol. Recognit., 2009, 22, 232–241.

[49] M.V. Rekharsky, Y. Inoue, Wiley–VCH., 2008, 199–230.

[50] G.R. Rezaei Behbehani, M. Shalbafan , N. Gheibi, L. Barzegar , H. Rezaei Behbehani, N. Yaghdavaei, Z. Rezaei Behbehani. J. Biophysical Reviews and Letters, 2013, 452, 59-71.

[51] G.R. Rezaei Behbehani, J. Acta. Chim.Slov., 2005, 52, 282-285.

[52] G.R. RezaeiBehbehani, A. Taherkhani, L. Barzegar, A.A. Saboury, A. Divsalar. J. Sci. I. R. Iran., 2011, 22, 2-5.

[53] G.R. RezaeiBehbehani, E. Tazikeh, A.A. Saboury, J. Korean Chem. Soc., 2006, 2, 208-210.

[54] G.R. Rezaei Behbehani, S. Ghamamy. J.Thermochim. Acta., 2006, 444, 71-76.

[55] G. Rezaei Behbehani, S. Ghamamy, W.E. Waghorne, J. Thermochim.acta., 2006, 448, 37-42.

[56] G. Rezaei Behbehani, E. Tazikeh, A.A. Saboury. J. ActaChim. Slov., 2006, 53, 363-369.

[57] G. Rezaei Behbehani, J. Korean Chem. Soc., 2005, 2, 238-240.

[58] G. Rezaei Behbehani, W.E. Waghorne, J. Thermochimica Acta ., 2008,478, 1-5.

Iranian chemical communication

Application of the extended solvation theory to study the interaction of β-CD with interpolymer of PEO and PAA

References

References

Volume 5, Issue 3, pp. 237-363, Serial No. 16
July 2017
Pages 286-292

Application of the extended solvation theory to study the interaction of β-CD with interpolymer of PEO and PAA

References

References

Volume 5, Issue 3, pp. 237-363, Serial No. 16July 2017Pages 286-292

Volume 5, Issue 3, pp. 237-363, Serial No. 16
July 2017
Pages 286-292