Highly efficient and rapid synthesis of diverse hydantoin derivatives using nano-ordered ZnO catalyst under mechanochemical ball milling

Maddah, Bozorg

Document Type : Original Research Article

Author

Bozorg Maddah

Imam Hossein University, Tehran, Iran

Abstract

A mild and efficient one-pot three-component and environmentally benign approach for the synthesis of a wide range of hydantoin annulated derivatives has been described. A multi-component reaction between a carbonyl compounds (ketone or aldehyde), potassium cyanide and ammonium carbonate (as cyanating agent and amine source, respectively leads to the formation of hydantoins. The proposed optimized reaction conditions ,i.e. solvent-free conditions under ambient temperature in the presence of low amount of ZnOnano-catalyst, were very efficient resulting in the formation of the desired products with good to excellent yields. Furthermore, the presented methodology is in accord with green chemistry principles.
Keywords: Bucherer-Bergs; hydantoin derivatives; multicomponent reactions (MCRs); green chemistry.

Graphical Abstract

Keywords

Main Subjects

Organic chemistry

References

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Iranian chemical communication

Highly efficient and rapid synthesis of diverse hydantoin derivatives using nano-ordered ZnO catalyst under mechanochemical ball milling

References

References

Volume 5, Issue 1, pp. 1-120, Serial No. 14
January 2017
Pages 58-66

Highly efficient and rapid synthesis of diverse hydantoin derivatives using nano-ordered ZnO catalyst under mechanochemical ball milling

References

References

Volume 5, Issue 1, pp. 1-120, Serial No. 14January 2017Pages 58-66

Volume 5, Issue 1, pp. 1-120, Serial No. 14
January 2017
Pages 58-66