Document Type : Short communication
Authors
Department of Chemistry, Payame Noor University, PB BOX 19395-4697 Tehran, Iran
Abstract
New 6-(hydroxymethyl)-14, 16-dimethyl-13, 14, 16, 17-tetrahydro-6H-13, 17-epiminodibenzo [e, l] [1, 4] dioxacyclotridecin-15 (7H)-one (2a) was synthesized in good yield by the Petrenko–Kritchenko reaction of 2, 2'-((3-hydroxypropane-1, 2-diyl) bis (oxy)) bisbenzaldehyde (1a) with diethyl ketone in the mixture of ethanol and acetic acid as solvent in the presence of ammonium acetate. The compounds were characterized by elemental analyses, IR, 1H-NMR, 13C-NMR and mass spectrometry.
Keywords: Petrenko–Kritchenko condensation, Macrocyclic compound, Bisaldehyde, 6-(hydroxymethyl)-14, 16-dimethyl-13, 14, 16, 17-tetrahydro-6H-13, 17-epiminodibenzo [e, l] [1, 4] dioxacyclotridecin-15 (7H)-one, 2, 2'-((3 hydroxypropane-1, 2-diyl) bis (oxy)) bisbenzaldehyde
Graphical Abstract
![Synthesis and characterization of 6-(hydroxymethyl)-14, 16-dimethyl-13, 14, 16, 17-tetrahydro-6H-13, 17-epiminodibenzo [e, l] [1, 4] dioxacyclotridecin-15 (7H)-one](javascript:loadModal('Synthesis and characterization of 6-(hydroxymethyl ... ', 'data/icc/coversheet/491452056753.png'))
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Main Subjects
[6] A.T. Le, H.H. Truong, P.T.T. Nguyen, H.T. Pham, V.E. Kotsuba, A.T. Soldatenkov, V.N. Khrustalev, A.T. Wodajo, Macroheterocycles., 2014, 7(4), 386-390.
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