[BMIm]BF4-LiCl as an effective catalytic system for the synthesis of dicoumarols

Azimi, Seyyedeh Cobra; Rad-Moghadam, Kurosh

Document Type : Original Research Article

Authors

¹ Islamic Azad University, Rasht, Iran

² Department of Chemistry, Guilan University

Abstract

A homogeneous ionic liquid 1-butyl-3-methylimidazolium tetrafluoroborate doped with LiCl ([BMIm]BF4-LiCl) was found as catalyst solvents for the synthesis of dicoumarols by the condensation of 4-hydroxycoumarin and aldehyde at 80 ˚C. In this field, several types of aromatic aldehyde, containing electron-withdrawing groups as well as electron-donating groups, were rapidly changed to the corresponding derivatives in good to excellent yields. Application of this new homogeneous catalyst system offered the advantages of short reaction times, solvent-free conditions, high yields, and easy work-up procedure compared to the conventional methods of the syntheses. The ionic liquid can be recovered for the subsequent reactions and reused without any loss of efficiency.

Graphical Abstract

Keywords

Main Subjects

Organic chemistry

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Iranian chemical communication

[BMIm]BF4-LiCl as an effective catalytic system for the synthesis of dicoumarols

References

References

Volume 3, Issue 4, pp. 283-387, Serial No. 9
October 2015
Pages 356-366

[BMIm]BF4-LiCl as an effective catalytic system for the synthesis of dicoumarols

References

References

Volume 3, Issue 4, pp. 283-387, Serial No. 9October 2015Pages 356-366

Volume 3, Issue 4, pp. 283-387, Serial No. 9
October 2015
Pages 356-366