@article { author = {Hasanpour, Foroozan and Taei, Masoumeh and Fouladgar, Masoud and Salehi, Mehdi}, title = {Au nano dendrites/composition optimized Nd-dopped cobalt oxide as an efficient electrocatalyst for ethanol oxidation}, journal = {Iranian chemical communication}, volume = {8}, number = {1}, pages = {102-111}, year = {2020}, publisher = {}, issn = {2423-4958}, eissn = {2345-4806}, doi = {10.30473/icc.2020.9788}, abstract = {In this study, Nd-doped cobalt oxide (Nd-Co3O4) nanoparticles were prepared by a combustion synthesis procedure using Co(acac)3 complex. The nanoparticles were characterized by infrared spectroscopy (IR), X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDX). Then, the effect of Nd-Co3O4 on the electrocatalytic activity of gold nanodendrites (AuNDs) electrodeposited on a glassy carbon electrode (GCE) for ethanol oxidation was studied. The results showed that the Nd-Co3O4/AuNDs/GCE presents higher active surface area and current density (about 2 times) for the ethanol oxidation compared with the AuNDs/GCE.  Cyclic voltammetry and chrono-potentiometry methods proved that the Nd-Co3O4/AuNDs/GCE is able to increase a long-term stability of electrode in alkaline ethanol fuel cell by providing OHads species at the surface of the catalysts. Consequently, the Nd-Co3O4/AuNDs/GCE, as an anodic electrode, reveals potent catalytic activity for ethanol oxidation in alkaline media.}, keywords = {Nd-doped cobalt oxide nanoparticles,Ethanol oxidation,Alkaline fuel cells,Au nano dendrites}, url = {https://icc.journals.pnu.ac.ir/article_9788.html}, eprint = {https://icc.journals.pnu.ac.ir/article_9788_5102ab3984e3dd415bee96b68d7ac3e9.pdf} }