Review Article Inorganic chemistry
Comparison of chelating ability of dipeptide (histidine-β-alanine) and (tetrakis(4-sulfonatophenyl)porphyrin) (TPPS4) for in vitro removal of toxic metals

Rahmatollah Rahimi; Maryam Khosravi; Mahboubeh Rabbani; Ebrahim Safavi

Volume 6, Issue 1, pp. 1-108, Serial No. 18 , January 2018, Pages 1-7

Abstract
  Peptides are one of the best candidates for drug development due to their high specificity and low toxicity and porphyrins are significant macromolecules in biological systems with important roles. In this works ynthesis of dipeptide (histidine-β-alanine) was done by solid-phase peptide synthesis ...  Read More

Comparison of chelating ability of dipeptide (histidine-β-alanine) and (tetrakis(4-sulfonatophenyl)porphyrin) (TPPS4) for in vitro removal of toxic metals


Original Research Article Analytical chemistry
Preconcentration of acrylamide with dispersive liquid-liquid microextraction based on solidification of floating organic drop prior to determination by HPLC

Shaghayegh Mohebi; Ali Mazloomifar

Volume 6, Issue 1, pp. 1-108, Serial No. 18 , January 2018, Pages 8-18

Abstract
  A novel, rapid, simple and sensitive dispersive liquid-liquid microextraction method based on the solidification of floating organic drop (DLLME-SFO) combined with high performance liquid chromatography-ultra violet detection (HPLC-UV) was used to determine acrylamide in potato chips. The derivation ...  Read More

Preconcentration of acrylamide with dispersive liquid-liquid microextraction based on solidification of floating organic drop prior to determination by HPLC


Original Research Article Nanochemistry
MWCNT incorporated silica aerogel prepared by ambient pressure drying: A recyclable catalyst for multicomponent synthesis of benzylpyrazolyl coumarin at room temperature

Isak Rajjak Shaikh; Noor Mahmad Nabisaheb Maldar; Caroline Sunyong Lee; Rajendra Charandeo Pawar; Hyung-Ho Park; Uzma Khwaja-Husain Bangi

Volume 6, Issue 1, pp. 1-108, Serial No. 18 , January 2018, Pages 19-29

Abstract
  Multiwalled Carbon Nanotube (MWCNT) reinforced silica aerogel was synthesized in a very simple and cost effective sol - gel method. The process was followed by ambient pressure drying, and then the aerogel material was characterized by XRD, BET, SEM, EDX and FT-IR. 2.3 x 10-3 wt% MWCNTs were successfully ...  Read More

MWCNT incorporated silica aerogel prepared by ambient pressure drying: A recyclable catalyst for multicomponent synthesis of benzylpyrazolyl coumarin at room temperature


Original Research Article Physical chemistry
A spectroscopic study on Calf thymus DNA binding properties of nickel (II) complex with imidazole derivatives of 1,10-phenanthroline ligand

Alireza Amini khouzani; Nasrin Sohrabi; Nahid Rasouli; Mahboube Eslami Moghadam

Volume 6, Issue 1, pp. 1-108, Serial No. 18 , January 2018, Pages 30-38

Abstract
  In this study, a nickel (II) complex with 1,10-phenanthroline based ligand, [Ni(FIP)2](OAC)2 (1) with FIP = 2-(Furan-2-yl)-1H-Imidazole[4,5-f][1,10] phenanthroline as ligand was synthesized and characterized by spectroscopic methods and elemental analysis. The interaction of [Ni(FIP)2](OAC)2 (1) with ...  Read More

A spectroscopic study on Calf thymus DNA binding properties of nickel (II) complex with imidazole derivatives of 1,10-phenanthroline ligand


Original Research Article Inorganic chemistry
MgCaFe-layered double hydroxide (LDH) for congo red dye removal in aqueous solution

Zeynab Soltani; Hossein Salavati; Maryam Movahedi; Zahra Sadeghi

Volume 6, Issue 1, pp. 1-108, Serial No. 18 , January 2018, Pages 39-48

Abstract
  In this work, the ability of the MgCaFe- Layered double hydroxide (LDH) for congo red (CR) dye removal in aqueous solution was investigated. Various parameters such as initial dye concentrations, temperature, adsorbent dosage, pH effect and agitation rate were examined and optimal conditions (10 mgL-1 ...  Read More

MgCaFe-layered double hydroxide (LDH) for congo red dye removal in aqueous solution


Original Research Article Nanochemistry
Synthesis of HA nanoparticles in the presence of anionic and cationic polyelectrolyte

Kobra Akhavan Saravani

Volume 6, Issue 1, pp. 1-108, Serial No. 18 , January 2018, Pages 49-54

Abstract
  Nanosized hydroxyapatite (HA) powders have been synthesized by an inverse microemulsion system using cyclohexane, an anionic surfactant and aqueous solutions of calcium nitrate tetrahydrate and biammonium hydrogen phosphate in the presence of anionic and caionic polyelectrolyte with the inducement of ...  Read More

Synthesis of HA nanoparticles in the presence of anionic and cationic polyelectrolyte


Original Research Article Physical chemistry
Phase transfer catalyzed reaction of disodium salt of 1,3-dihydroxybenzene with propargyl bromide in solid-liquid biphasic condition

Venugopal Rajendran; Varathan Selvaraj; Pachaiyappan Abimannan

Volume 6, Issue 1, pp. 1-108, Serial No. 18 , January 2018, Pages 55-61

Abstract
  The present work describes, the reaction between disodium salt of 1,3-dihydroxybenzene (in situ formation) and propargyl bromide was carried out in a solid-liquid biphasic phase transfer catalytic system at 50°C. Higher selectivity of the bis-derivative (1,3-bis(prop-2-ynyloxy)benzene) was obtained ...  Read More

Phase transfer catalyzed reaction of disodium salt of 1,3-dihydroxybenzene with propargyl bromide in solid-liquid biphasic condition


Original Research Article Nanochemistry
ZrOCl2.8H2O@nano SiO2: a green and recyclable catalyst for the synthesis of benzimidazoles

Kobra Nikoofar; Shekoufe Moazzez Dizgarani

Volume 6, Issue 1, pp. 1-108, Serial No. 18 , January 2018, Pages 62-69

Abstract
  ZrOCl2.8H2O@nano SiO2 has been synthesized for the first time via a simple procedure and characterized by SEM (scanning electron microscopy), FT-IR, and EDX (energy-dispersive X-ray) techniques. The efficiency of the prepared nanostructure has been explored for the synthesis of benzimidazoles via the ...  Read More

ZrOCl2.8H2O@nano SiO2: a green and recyclable catalyst for the synthesis of benzimidazoles


Original Research Article Nanochemistry
Brassica oleraceae, a versatile plant for green synthesis of silver nanoparticles

Gholamhassan Imanzadeh; Raha Hadi

Volume 6, Issue 1, pp. 1-108, Serial No. 18 , January 2018, Pages 70-77

Abstract
  In the present paper, silver nanoparticles (AgNPs) were synthesized using the Brassica oleraceae fruit extract under the simple and eco-friendly conditions. The reaction between silver nitrate, as metal source, and aqueous extract of Brassica oleraceae fruit, as reductant agent, produced AgNPs in high ...  Read More

Brassica oleraceae, a versatile plant for green synthesis of silver nanoparticles


Original Research Article Inorganic chemistry
Two new Schiff base complexes; synthesis, characterization, NMR, IR and mass study of a number of [1+1] Cd(II) complexes

Reza Golbedaghi; Alirza Salehi

Volume 6, Issue 1, pp. 1-108, Serial No. 18 , January 2018, Pages 78-86

Abstract
  In this paper we report the synthesis and characterization of two new binuclear Cd(II) macrocyclic Schiff base complexes [CdL23pydfp(NO3)], (1), and [CdL33pydfp(NO3)], (2). [1+1] cyclocondensation of L23py = N-(2-pyridylmethyl)-N-(3-aminpropyl)-1,3-diaminoethane and L33py = N-(3-pyridylmethyl)-N-(3-aminpropyl)-1,3-diaminopropane ...  Read More

Two new Schiff base complexes; synthesis, characterization, NMR, IR and mass study of a number of [1+1] Cd(II) complexes


Original Research Article Organic chemistry
Nickel ferrite as a recyclable nanocatalyst for synthesis of novel highly substituted 1,4-dihydropyrano[2,3-c]pyrazole derivatives

Mohammad Reza Poor Heravi; Naheed Morsalie

Volume 6, Issue 1, pp. 1-108, Serial No. 18 , January 2018, Pages 87-96

Abstract
  Highly substituted 1,4-dihydropyrano[2,3-c]pyrazole derivatives were synthesized by four-component reaction of aromatic aldehydes, malononitrile, ethyl acetoacetate and various phenylhydrazine, using nickel ferrite as a recyclable nanocatalyst by a grinding method under solvent-free and thermal conditions. ...  Read More

Nickel ferrite as a recyclable nanocatalyst for synthesis of novel highly substituted 1,4-dihydropyrano[2,3-c]pyrazole derivatives


Original Research Article Nanochemistry
Fe2V4O13 assisted hetero-Fenton mineralization of methyl orange under UV-A light irradiation

Kaliyamoorthy Gowthami; Palusamy Suppuraj; Ganesamoorthy Thirunarayanan; Balu Krishnakumar; Abílio José Fraga do Nascimento Sobral; Meenakshisundaram Swaminathan; Inbasekaran Muthuvel

Volume 6, Issue 1, pp. 1-108, Serial No. 18 , January 2018, Pages 97-108

Abstract
  Fe2V4O13 is prepared and characterized by X-ray diffraction (XRD), Fourier transform infrared (FT-IR), UV-diffuse reflectance spectroscopy (UV-DRS), high resolution scanning electron microscopy (HR-SEM) using energy dispersive X-ray spectroscopy (EDX) analysis. The hetero-Fenton catalyst can be used ...  Read More

Fe2V4O13 assisted hetero-Fenton mineralization of methyl orange under UV-A light irradiation