Document Type : Original Research Article

Authors

1 Chemistry Departmean, Farhangiyan University, Tehran, Iran

2 Young Researchers Club, Tabriz Branch, Islamic Azad University, Tabriz, Iran

3 Department of Mathematics and Statistics, University of Guelph, Guelph ON N1G 2W1, Canada

10.30473/icc.2021.56572.1672

Abstract

Some bis(3-methylphenyl)sulfoxide aza macrocycles (3–8) were synthesized based on the conventional route from the reaction of corresponding bis(3-methylphenyl)sulfoxide diester and diamines in refluxing methanol in good yields. Bis(3-methylphenyl)sulfoxide diester was synthesized from the reaction of 2-[(2-hydroxy-5-methylphenyl)sulfinyl]-4-methylphenol and methyl chloroacetate. The structures of these compounds were confirmed using IR, 1H NMR, 13C NMR and Mass spectroscopy.

Graphical Abstract

Efficient synthesis of bis(3-methylphenyl)sulfoxide aza macrocycles from a bis(3-methylphenyl)sulfoxide diester and diamine derivatives

Keywords

Main Subjects

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