ORIGINAL_ARTICLE
Multivariate curve resolution-alternating least squares applied to kinetic spectrophotometric data for the determination of mixtures of aliphatic amines
Kinetic spectrophotometric second order data based on the reaction of 1,2-naphthoquinone-4-sulphonate (NQS) coupled with multivariate curve resolution-alternating least squares (MCR-ALS) has been proposed for simultaneous determination of ethylamine, propylamine and butylamine. Using second-order advantage, MCR-ALS methodology can solve problems of quantitation of analyte in the presence of unknown and uncalibrated interferences. Ethylamine, propylamine and butylamine react differentially with NQS at pH 9.5. Therefore, determination of these amines has been carried out due to the difference between their reaction rates. Quantitative determination of each amine in the mixture is performed using a synthetic solution as standard containing only the amine of interest. The MCR-ALS results are evaluated by the residuals and parameters such as lack of fit. The quantitative determination of these amines in different synthetic mixtures and some real samples such as river water, well water, tap water and soil has been performed and the results have been found to have good recoveries.
https://icc.journals.pnu.ac.ir/article_5317_4996f83fc7cfe2a4d23782093d6ab913.pdf
2019-01-01
1
14
10.30473/icc.2018.42439.1478
MCR-ALS
aliphatic amines
Kinetics
UV/Vis spectroscopy
Masoumeh
Hasani
hasani@basu.ac.ir
1
Faculty of Chemistry, Bu-Ali Sina University, Hamedan, Iran
LEAD_AUTHOR
Tayebeh
Sayarpour
tsayarpour@ymail.com
2
Bu-Ali Sina University
AUTHOR
Abbas
Karami
abaskarami1367@gmail.com
3
Bu-Ali Sina University
AUTHOR
Masoud
Shariati-rad
momasrad@gmail.com
4
Razi University
AUTHOR
[1] M. Windholz, S. Budavari, L.Y.
1
Stroumtsos, M.N. Fertig, “The Merck Index”, Merck &co, New Jersey, 1976.
2
[2] F. Sacher, S. Lenz, H. J. Brauch, J. Chromatogr. A, 1997, 764, 85- 93.
3
[3] Y. Moliner Martinez, C. MolinsLegua, P. Campı́nsFalcó, Talanta, 2004, 62, 373-382.
4
[4] S. Meseguer Lloret, C. MolinsLegua, J. Verdú Andrés, P. Campı́nsFalcó, J. Chromatogr. A, 2004, 1035, 75-82.
5
[5] P.F. Gao, Z.X. Zhang, X.F. Guo, H. Wang, H.S. Zhang, Talanta , 2011, 84, 1093-1098.
6
[6] J.S. Li, H. Wang, L. W. Cao, H. S Zhang, Talanta, 2006, 69, 1190-1199.
7
[7] M. Kaykhaii, S. Nazari, M. Chamsaz, Talanta, 2005, 65, 223-228.
8
[8] A. Terashi, Y. Hanada, A. Kido, R. Shinohara, J. Chromatogr. A, 1990, 503, 369-375.
9
[9] C. Deng, N. Li, L. Wang, X. Zhang, J. Chromatogr. A, 2006, 1131, 45-50.
10
[10] I.A. Darwish, H.H. Abdine, S.M. Amer, L.I. Al-Rayes, Spectrochim. Acta A, 2009, 72, 897-902.
11
[11] M. Hasani, L. Yaghoubi, H. Abdollahi, Anal. Biochem., 2007, 365,74-81.
12
[12] Y. Ni, C. Huang, S. Kokot, Anal. Chim. Acta , 2007, 599, 209-218.
13
[13] Y. Ni, W. Xiao, S. Kokot, J. Hazard. Mater., 2009, 168, 1239-1245.
14
[14] M. Shahpar, S. Esmaeilpoor, Chem. Method, 2017, 1, 98-120.
15
[15] X.H. Zhang, H.L. Wu, J.Y. Wang, Y. Chen, Y.J. Yu, C.C. Nie, C. Kang, D.Z. Tu, R.Q. Yu, J. Pharm. Anal., 2012, 2, 241-248.
16
[16] A.C. Olivieri, Anal. Chem., 2008, 80, 5713-5720.
17
[17] R.Tauler, Chemometr. Intell. Lab. Syst., 1995, 30,133-146.
18
[18] M.J. Culzonin, H.C. Goicoechea , G.A. Ibanez, V.A. Lozano, N.R. Marsili, A.C. Olivieri, A.P. Pagani, Anal. Chim. Acta, 2008, 614, 46-57.
19
[19] A. Naseri, B. Ghasemzadeh, K. Asadpour-Zeynali1, J IRAN CHEM SOC, 2016, 13, 679–687.
20
[20] A. Naseri, M. Bahram, M. Mabhooti, J. Braz. Chem. Soc. 2011, 22, 2206-2215.
21
[21] M. Shariati-Rad, M. Irandoust, S. Mohamadi, Food Anal. Methods, 2017, 10, 694-703.
22
[22] S.F. Li, H.L. Wu,A.L. Xia, S.H. Zhu, J.F. Nie, Y.J. Yu, Anal. Sci., 2009, 25, 1231-1236.
23
[23] G. Ahmadi, H. Abdollahi,Chemometr. Intell. Lab. Syst., 2013, 120, 59-70.
24
[24]J. Saurina, S. Hernández-Cassou, Analyst, 1999, 124, 745-749.
25
[25] H.Y. Wang, L.X. Xu, Y. Xiao, J. Han, Spectrochim. Acta A, 2004, 60, 2933-2939.
26
[26] A.A. Elbashir, A.A. Ahmed, Sh.M. Ali Ahmed, H.Y. Aboul-Enein, Appl. Spectrosc. Rev., 2012, 47, 219-232.
27
[27] S.M. Ali Ahmed, A.A. Elbashir, H.Y. Aboul-Enein, Arab J Chem., 2015, 8, 233–239.
28
[28] A. de Juan, S.C. Rutan, R. Tauler, D.L. Massart, Chemometr. Intell. Lab. Syst., 1998, 40, 19–32.
29
[29] A. De Juan, M. Maeder, M. Martínez, R. Tauler, Anal. Chim. Acta, 2001, 442, 337-350.
30
[30] M. Maeder, Anal. Chem., 1987, 59, 527-530.
31
[31] W. Windig, D.A. Stephenson, Anal. Chem., 1992, 64, 2735-2742.
32
[32] F.C. Sánchez, J. Toft, B. Van den Bogaert, D. L. Massart, Anal. Chem., 1996, 68, 79-85.
33
[33] F.C. Sánchez, B.G. M. Vandeginste, T.M. Hancewicz, D.L. Massart, Anal. Chem., 1997, 69, 1477-1484.
34
[34] G.H. Golub, C.F. Van Loan, Matrix Computation, Johns Hopkins University Press, third edition, 1989.
35
[35] C.B. Zachariassen, J. Larsen, F. Van den Berg, R. Bro, A. De Juan, R. Tauler, Chemometr. Intell. Lab. Syst., 2006, 83, 13–25.
36
[36] T. Azzouz, R. Tauler, Talanta, 2008, 74, 1201–1210.
37
[37] R. Tauler, A. De Juan, Multivariate curve resolution home page, http://www.ub.es/gesq/mcr/mcr.htm.
38
[38] Y. Hashimoto, M. Endo, K. Tomiaga, S. Inuzuka, M. Moriyasu, Microchim. Acta, 1978, 7, 493-504.
39
[39] R. Tauler, D. Barceló, Trends Anal. Chem., 1993, 12, 319-327.
40
[40] J. M. Amigo, A. de Juan, J. Coello, S. Maspoch, Anal. Chim. Acta, 2006, 567, 236-244.
41
ORIGINAL_ARTICLE
One-pot synthesis of highly regioselective β-azido alcohols catalyzed by Brønsted acidic ionic liquids
In this protocol, 3-(2-carboxybenzoyl)-1-methyl-1H-imidazol-3-ium chloride [Cbmim]Cl and sulfonic acid functionalized pyridinium chloride [pyridine-SO3H]Cl as a new, reusable, and green Brønsted acidic ionic liquid (BAIL) catalyst were synthesized and successfully used for the one-pot ring opening of epoxide with sodium azide (NaN3) in water at room temperature. Epoxides under ring-opening easily with NaN3 in the presence of [Cbmim]Cl and [pyridine-SO3H]Cl to afford the corresponding β-azido alcohols as attractive and interesting materials in drug design and pharmaceutics compounds in high yield with good regioselective under mild reaction conditions. In this protocol, 3-(2-carboxybenzoyl)-1-methyl-1H-imidazol-3-ium chloride [Cbmim]Cl and sulfonic acid functionalized pyridinium chloride [pyridine-SO3H]Cl as a new, reusable, and green Brønsted acidic ionic liquid (BAIL) catalyst were synthesized and successfully used for the one-pot ring opening of epoxide with sodium azide (NaN3) in water at room temperature. Epoxides under ring-opening easily with NaN3 in the presence of [Cbmim]Cl and [pyridine-SO3H]Cl to afford the corresponding β-azido alcohols as attractive and interesting materials in drug design and pharmaceutics compounds in high yield with good regioselective under mild reaction conditions.
https://icc.journals.pnu.ac.ir/article_7646_49929f7462e386f328220c7b4a6c486c.pdf
2019-01-01
15
28
10.30473/icc.2019.7646
[Cbmim]Cl
[pyridine-SO3H]Cl
epoxide
ring opening
azidoalcohols
Water
Sarvin
Mohammadi-Aghdam
sarvin.s108@yahoo.com
1
Department of Chemistry, Payame Noor University, PO box 19395-3197, Tehran, Iran
AUTHOR
Hadi
Jabbari
hadijabbari@yahoo.com
2
Department of Chemistry, Payame Noor University, PO BOX 19395-4697 Tehran, Iran
AUTHOR
Omidali
Pouralimardan
pouralimardan@gmail.com
3
Department of Chemistry, Payame Noor University, PO BOX 19395-4697 Tehran, Iran
AUTHOR
Fater
Divsar
divsar@gmail.com
4
Department of Chemistry, Payame Noor University, PO BOX 19395-4697 Tehran, Iran
AUTHOR
Issa
Amini
issa_amini@ymail.com
5
Department of Chemistry, Payame Noor University, PO BOX 19395-4697 Tehran, Iran
AUTHOR
Sami
Sajjadifar
ss_sajjadifar@yahoo.com
6
Department of Chemistry, Payame Noor University, PO BOX 19395-4697 Tehran, Iran
LEAD_AUTHOR
ORIGINAL_ARTICLE
Preparation, characterization and Photo-inactivation of cellulose nanocrystals impregnated with meso-tetrakis(4-nitrophenyl)porphyrin
In this study, cellulose nanocrystals (CNC) was prepared and meso-tetrakis(4-nitrophenyl)porphyrin (TNPP) was immobilized on it. The product was identified by techniques of UV-Vis, fourier transform infrared (FT-IR), diffuse reflectance UV-Vis spectroscopy (DRS), energy-dispersive X-ray spectroscopy (EDX) and scanning electron microscopy (SEM). The effect of an amount of a loaded porphyrin compound containing the nitro group on CNC was investigated against a typical Gram negative bacterium, Pseudomonas aeruginosa, and a typical Gram positive bacterium, Bacillus subtilis, under visible light irradiation. The results indicated that CNC incorporated with 14.9% TNPP has a good effect on the photo-inactivation of P. aeruginosa and can be used in the textile, biomedicine, biomaterials engineering, membranes and polymer nanocomposites.
https://icc.journals.pnu.ac.ir/article_4217_3483efc06900efcddb06c47cd2f21637.pdf
2019-01-01
29
38
10.30473/icc.2019.4217
Bacillus subtilis
binding test
Cellulose nanocrystals
Photodynamic antimicrobial chemotherapy
pseudomonas aeruginosa
TNPP
Fatemeh
Fayyaz
f.fayyaz@yahoo.com
1
Department of Science, Payame Noor University, P.O. BOX 19395-3697 Tehran, Iran
LEAD_AUTHOR
Mahboubeh
Rabbani
m_rabani@iust.ac.ir
2
Bioinorganic chemistry laboratory, Department of Chemistry, Iran University of Science and Technology, Narmak, Tehran, 16846-13114, Iran.
AUTHOR
Rahmatollah
Rahimi
rahmatollah.rahimi93@gmail.com
3
Bioinorganic chemistry laboratory, Department of Chemistry, Iran University of Science and Technology, Tehran, 16846-13114, Iran.
AUTHOR
Mehdi
Rassa
rassa62@gmail.com
4
Department of Biology, Faculty of Science, Guilan University, Rasht, Iran
AUTHOR
[1] J.I. Moran,V.A. Alvarez,V.P. Cyras, A. Vazquez, Cellulose, 2008, 15, 149–159.
1
[2] Y. Zhang Xiao-Bin Lu, C. Gao, Wei-Jun Lv, Ju-Ming Yao, Journal of Fiber Bioengineering & Informatics, 2012, 5, 263–271.
2
[3] C. Ringot,V. Sol, R. Granet, P. Krausz, Materials Letters, 2009, 63, 1889–1891. [4] N. Drogat, R. Granet, C. Le Morvan, G. Bégaud-Grimaud, P. Krausz,V. Sol, Bioorganic & Medicinal Chemistry Letters, 2012, 22, 3648-3652.
3
[5] J.P. Mbakidi, K. Herke, S. Alves, V. Chaleix, R. Granet, P. Krausz, S. Leroy-Lhez, T.S. Ouk, V. Sol, Carbohydrate Polymers, 2013, 91, 333-338.
4
[6] C. Ringot,V. Sol, M. Barrière, N. Saad, P. Bressollier, R. Granet, P. Couleaud, C. Frochot, P. Krausz, Biomacromolecules, 2011, 12, 1716–1723.
5
[7] X.Y. Liu, H.M. Wang, J.Q. Jiang, J.H. Xiao, R.L. Gao, F.Y. Lin, Chemico-Biological Interactions, 2008, 172, 154–158.
6
[8] S. Banfi, E. Caruso, L. Buccafurni, V. Battini, S. Zazzaron, P. Barbieri, V. Orlandi, Journal of photochemistry and photobiology B Biology, 2006, 85, 28–38.
7
[9] C.M. Cassidy, R.F. Donnelly, M.M. Tunney, Journal of Photochemistry & Photobiology, B: Biology, 2010, 99, 62–66.
8
[10] A. Peèkaitytëa, R. Daugelavièiusa, A. Sadauskaitëa, V. Kirvelienëa, R. Bonnettb, E. Bakienë, 2005, No.1, 41–46.
9
[11] E.V. Alopina, T.A. Ageeva, A.V. Lyubimtse, O.Yu. Kuznetsovc, S.A. Syrbu, Os.I. Koifman, Macroheterocycles, 2012, 5, 76–80.
10
[12] R. Luguya, L. Jaquinod, F.R. Fronczek, M. Graca, H. Vicente, K.M. Smith, Tetrahedron, 2004, 60, 2757–2763.
11
[13] M.A. Schiavon, L.S. Iwamoto, A.G. Ferreira, Y. Iamamoto, M.V. B. Zanoniand M.das D. Assis, J. Braz. Chem. Soc.,2000, 11, 458–466.
12
[14] K. Rajesh, A. Kalilur Rahiman, K. Shanmuga Bharathi, S. Sreedaran,V. Gangadevi,V. Narayanan, Bull. Korean Chem. Soc., 2010, 31, 2656–2664.
13
[15] J. Zhang, X. Wu, X. Cao, F. Yang, J. Wang, X. Zhoua, X. Lian Zhang, Bioorganic & Medicinal Chemistry Letters, 2003, 13, 1097–1100.
14
[16] H. Ashkenazi,Y. Nitzan, D. Ga, Photochemistry and Photobiology, 2003, 77, 186–191.
15
[17] V. Sol, P. Branland, V. Chaleix, R. Granet, M. Guilloton, F. Lamarche, B. Verneuil, P. Krausz, Bioorganic & Medicinal Chemistry Letters, 2004, 14, 4207–4211.
16
[18] D. Lazzeri, M. Rovera, L. Pascual, E.N. Durantini, Photochemistry and Photobiology, 2004, 80 286–293.
17
[19] V.T. Orlandi, E. Caruso, S. Banfi, P. Barbieri, Photochemistry and Photobiology, 2012, 88, 557–564.
18
[20] R. Rahimi, F. Fayyaz, M. Rassa, Materials Science and Engineering C, 2016, 59, 661–668.
19
[21] R. Rahimi, F. Fayyaz, M. Rassa, M. Rabbani, Iranian Chemical Communication, 2016, 4, 175-185.
20
[22] E. Feese, H. Sadeghifar, H.S. Gracz, D.S. Argyropoulos, R.A. Ghiladi, Biomacromolecules, 2011, 12, 3528–3539.
21
[23] F. Fayyaz, R. Rahimi, M. Rassa, A. Maleki, Water Science & Technology: Water Supply, 2015, 15(5), 1099-1105.
22
[24] T. Kangwanwong, W. Pluempanupat,W. Parasuk, H.E. Keenan, A. Songsasen, ScienceAsia, 2012, 38, 278–282.
23
[25] A. Allen, J. Foulk, G. Gamble, J. Cotton Sci., 2007, 11, 68–74.
24
[26] J. Alongi, C. Colleoni, G. Rosace, G. Malucell, J. Therm.Anal.Cal., 2012, 110, 1207–1216.
25
[27] C. Chung, M. Lee, E.K. Choe, Carbohydrate Polymer., 2004, 58, 417–420.
26
[28] R. Dosselli, C. Tampieri, R. RuizGonzález, S.D. Munari, X. Ragàs, D. Sánchez-García, M. Agut, S. Nonell, E. Reddi, M. Gobbo, J. Med. Chem, 2013, 56, 1052−1063.
27
[29] S. Mordon, C. Cochrane, J.B. Tylcz, N. Betrouni, L. Mortier, V. Koncar, Photodiag. Photodyn. Therap., 2015, 12, 1–8.
28
[30] S. Senthilkumar, R. Hariharan, A. Suganthi, M. Ashokkumar, M. Rajarajan, K. Pitchumani, Powder Technology, 2013, 237, 497–505.
29
[31] M. Krouit, R. Granet, P. Krausz, Eur. Polym. J., 2009, 45, 1250–1259.
30
ORIGINAL_ARTICLE
Prediction of IC50 of 2,5-diaminobenzophenone organic derivatives using informatics-aided genetic algorithm
In the present paper, informatics-aided quantitative structure activity relationship (QSAR) models using genetic algorithm-partial least square (GA-PLS), genetic algorithm-Kernel partial least square (KPLS), and Levenberg-Marquardt artificial neural network (LM ANN) approach were constructed to access the antimalarial activity (pIC50) of 2,5-diaminobenzophenone derivatives. Comparison of errors and correlation coefficients obtained by the models it was shown that the LM ANN approach works with a high correlation coefficient and low prediction error. This model was applied to the prediction of pIC50 values of 2,5-diaminobenzophenone derivatives. Applying the extended model to a dataset of 20 compounds demonstrate the reliability and accuracy of the model. Comparing three models revealed the superiority of the L-M ANN to predict the pIC50 of 2,5-diaminobenzophenones derivatives.
https://icc.journals.pnu.ac.ir/article_4932_4aa9b8e65178146b3fd3b2ad1df7d236.pdf
2019-01-01
39
51
10.30473/icc.2018.4932
P. falciparum malaria
antimalarial compounds
2,5-diaminobenzophenones
QSAR
Rashid
Heidarimoghadam
r_farmany@yahoo.com
1
Department of Ergonomics, Health Sciences Research Center, School of Public Health, Hamadan University of Medical Sciences, Hamadan, IRAN.
AUTHOR
Seyede Shima
Mortazavi
smortazavi58@yahoo.com
2
Young Researchers & Elite Club, Hamedan Branch, Islamic Azad University, Hamedan, IRAN
AUTHOR
Abbas
Farmany
a.farmany@usa.com
3
Dental Research Center, School of Dentistry, Hamadan University of Medical Sciences, Hamadan, IRAN
LEAD_AUTHOR
[1] V. Moorthy, Z. Reed, P. G. Smith, Vaccine, 2007, 25, 5115-5123.
1
[2] S. Mharakurwa, Ph. E. Thuma, D. E. Norris, M. Mulenga, V. Chalwe, J. Chipeta, Sh. Munyati, S. Mutambu, P. R. Mason, Acta Trop., 2012, 13, 531-547.
2
[3] R. I. Chima, C. A. Goodman, A. Mills, Health Pol., 2003, 63,17-36
3
[4] L. Hviid, Microbes and Infec., 2007, 9, 772-776
4
[5] M. Nekoei, Iran. Chem. Commun., 2017, 5, 79-98
5
[6] M. Bouachrin, Y. Bouakarai, F. Khalil,Chem. Method., 2017, 1, 173-193
6
[7] (a) M. Shahpar, S. Esmaeilpoor, Asian J. Green Chem., 2017, 1(2), 116-129. DOI: 10.22631/ajgc.2017.94413.1010 (b) M. Shahpar, S. Esmaeilpoor, Chem. Method., 2017, 1(2), 98-120. DOI: 10.22631/chemm.2017.96397.1008
7
[8]H. Noorizadeh, S. Esmaeilpoor, Z. Moghadam, S. Nosratolahy, Iran. Chem. Commun., 2014, 2, 283-299
8
[9] R. A. Cormanich, M. P. Freitas, R. Rittner, J. Braz. Chem. Soc., 2011, 22, 37-642.
9
[10] H. Noorizadeh, A. Farmany, M. Noorizadeh, Quim. Nova, 2011, 34, 1398-1404.
10
[11] E. Pourbasheer, S. Riahi, MR. Ganjali, P. Norouzi, Eur. J. Med. Chem., 2009, 44, 5023–5028.
11
[12] N. Singh, A. Basant, S. Malik, G J. Sinha, Intell. Lab. Syst.,2009, 99, 150-160
12
[13] B. Jančić-Stojanović, D. Ivanović, A. Malenović, M. Medenica, Talanta, 2009, 78, 107–112.
13
[14] M. Jalali-Heravi, M. Asadollahi-Baboli, P. Shahbazikhah, Eur. J. Med. Chem., 2008, 43, 548-556.
14
[15] H. Noorizadeh, A. Farmany, Drug. Test. Anal., 2012, 4, 151-157.
15
[16] AA. D'Archivio, M. A. Maggi, P. Mazzeo, F. Ruggieri, Anal. Chim. Acta.2008, 628, 162 – 172.
16
[17] B. Jančić, M. Medenica, D. Ivanović, S. Janković, A. Malenović, J Chromatogr A, 2008, 1189, 366-373.
17
[18] R. Todeschini, V. Consonni, Handbook of Molecular Descriptors, 2000. Wiley/VCH, Weinheim.
18
[19] (a) O. Deeb, Chemom. Intell. Lab. Syst., 2010, 104, 181-194. (b) S. Sajjadifar, Chem. Method., 1(1), 1-11. DOI: 10.22034/chemm.2017.49740
19
[20] D. Pran Kishore, C. Balakumar, A. Raghuram Rao, P. P. Roy, K. Roy, Bioorg. Med. Chem. Lett., 2011, 21, 818-823
20
[21] M. Arab Chamjangali, M. Beglari, G. Bagherian, J. Mol. Graphics. Modell., 2007, 26, 360-367.
21
[22] H. Noorizadeh, A. Farmany, J. Chinese Chem. Soc., 2010, 57, 1268-1277.
22
[23] H. Noorizadeh, A. Farmany, A. Khosravi, J. Chin. Chem. Soc, 2010, 57, 982-991.
23
[24] A.K. Zhokhov, A.Y. Loskutov, I.V. Rybal’chenko, J. Anal. Chem., 2018, 73, 207-220.
24
[25] N. Fan, S. Zhang, T. Sheng, L. Zhao, Z. Liu, J. Liu, X. Wang, Chem. Bio. Drug Des., 2018, 398-407.
25
[26] U. Judycka, K. Jagiello, M. Gromelski, L. Bober, J. Błażejowski, T. Puzyn, J. Chromatogr. B, 2018, 1095, 8-14.
26
ORIGINAL_ARTICLE
New pyrazolone derivatives synthesis: comparison of the catalytic effect of three typically different Brønsted acid catalysts on the reaction progression
Via the one-pot condensation reaction of ethyl acetoacetate, aromatic aldehydes, 2,4-dinitrophenylhydrazine, and β-naphthol; new pyrazolone derivatives were synthesized in the presence of three Brønsted acid catalysts. These Brønsted acid catalysts are Silica sulfuric acid (SSA), tetra-n-butyl ammonium hydrogen sulfate (TBAHSO4) and [2,2′-Bipyridine]-1,1′-diium tricyanomethanide {[2,2′-BPyH][C(CN)3]2}. Each of these combinations has its own characteristics. SSA is a heterogeneous catalyst. TBAHSO4 is a phase transfer catalyst and {[2,2′-BPyH][C(CN)3]2} is an ionic liquid. We compared the obtained results of these catalysts. In most cases, the results were comparable. But, sometimes TBAHSO4 and {[2,2′-BPyH][C(CN)3]2} give the better results to the SSA in term of reaction time and yields. Even though, isolation of SSA from products was easier than the separation of two other catalysts.
https://icc.journals.pnu.ac.ir/article_4937_77b53189830f19dff47fea9e85aaa117.pdf
2019-01-01
52
62
10.30473/icc.2018.4937
Pyrazolone
silica sulfuric acid
tetra-n-butyl ammonium hydrogen sulfate
[2
2′-bipyridine]-1
1′-diium tri-cyanomethanide
Gholamabbas
Chehardoli
cheh1002@gmail.com
1
Department of Medicinal Chemistry, School of Pharmacy, Hamedan University of Medical Sciences
LEAD_AUTHOR
Navid
Mansouri
mr.n.mansouri@gmail.com
2
Department of medicinal chemistry, School of Pharmacy, Hamadan University of Medical Sciences, Hamadan 6517838695, Iran.
AUTHOR
[1] M.R. Poor Heravi, M. Amirloo, Iran. Chem. Commun., 2014, 3, 73-84.
1
[2] H. Veisi, A. Maleki, Y. Farokhzad, Iran. Chem. Commun., 2017, 5, 217-226.
2
[3] Z. Vafajoo, D. Kordestani, S. Vafajoo, Iran. Chem. Commun., 2018, 6, 293-299.
3
[4] J. Zhou, W.J. Huang, G.F. Jiang, Org. Lett., 2018, 20, 1158-1161.
4
[5] M.T. El Sayed, M.A.M.S. El-Sharief, E.S. Zarie, N.M. Morsy, A.R. Elsheakh, A. Voronkov, et al., Bioorg. Medicin. Chem. Lett., 2018, 28, 952-957.
5
[6] A. Jasiecka, T. Maślanka, J. Jaroszewski, Pol. J. Vet. Sci., 2014, 17, 207-214.
6
[7] M. Reuvers, C. Schaefer. Analgesics and anti-inflammatory drugs. Drugs During Pregnancy and Lactation (Second Edition): Elsevier; 2007, 28-56.
7
[8] E. Göres, J. Kossowicz, H. Schneider, Med. Monatsschr. Pharm., 2004, 27, 72-76.
8
[9] H. Yoshino, A. Kimura, Amyotroph. Lat. Scler., 2006, 7, 247-251.
9
[10] Y. Higashi, D. Jitsuiki, K. Chayama, M. Yoshizumi, Recent Adv. Cardiovasc. Drug Discov., 2006, 1, 85-93.
10
[11] Y. Kakiuchi, M. Oyama, M. Nakatake, Y. Okamoto, H. Kai, H. Arima, et al., Cytologia, 2010, 75, 177-183.
11
[12] A. Ziarati, J. Safaei-Ghomi, S. Rohani, Ultrason. Sonochem., 2013, 20, 1069-1075.
12
[13] W. Wang, S.X. Wang, X.Y. Qin, J.T. Li, Synth. Commun., 2005, 35, 1263-1269.
13
[14] A. Hasaninejad, M. Shekouhy, A. Zare, S.H. Ghattali, N. Golzar, J. Iran. Chem. Soc., 2011, 8, 411-423.
14
[15] M.A. Zolfigol, G. Chehardoli, S.E. Mallakpour, Synth. Commun., 2003, 33, 833-841.
15
[16] M.A. Zolfigol, N. Mansouri, S. Baghery, Synlett, 2016, 27, 1511-1515.
16
[17] S. Sajjadifar, M.A. Zolfigol, N. Javaherneshan, G. Chehardoli, Bulg. Chem. Communi., 2017, 49, 87-91.
17
[18] M.A. Zolfigol, S. Sajjadifar, G. Chehardoli, N. Javaherneshan, Sci. Iran., 2014, 21, 2059-2065.
18
[19] S. Sajjadifar, M.A. Zolfigol, G. Chehardoli, S. Miri, P. Moosavi, Int. J. ChemTech Res., 2013, 5, 422-429.
19
[20] G. Chehardoli, M.A. Zolfigol, S.B. Azimi, E. Alizadeh, Chin. Chem. Lett., 2011, 22, 827-830.
20
[21] A. Hasaninejad, M.A. Zolfigol, G. Chehardoli, M. Mokhlesi, J. Serb. Chem. Soc., 2010, 75, 307-316.
21
[22] A.J. Pardey, A.B. Rivas, C. Longo, T. Funaioli, G. Fachinetti, J. Coord. Chem., 2004, 57, 871-882.
22
ORIGINAL_ARTICLE
Study of structure and thermal properties of styrene-butylacrylate copolymer with OMMT nanocomposite emulsions
(St-co-BA) polymer through montmorillonite (MMT) nanocomposite emulsion is prepared by in situ intercalative emulsion polymerization of styrene (St), butyl acrylate (BA) in the presence of organic modified montmorillonite (OMMT) with different OMMT contents (0, 0.5, 1.0, 1.5, and 2.0 wt%). The synthetic compounds are characterized by FTIR, XRD. The nanocomposite emulsions are characterized by applying FTIR, SEM, TEM, TGA and DSC techniques in order to investigate the structure and the thermal properties of the coplymer. The properties of the nanocomposite emulsions containing OMMT are better than styrene-acrylate emulsion. The study of monomer conversion versus time and different OMMT contents indicates that the polymerization rate is decreased by increasing the concentration of styrene and OMMT. Consequently the properties of the nanocomposite emulsion containing 1 wt % OMMT are better than other contents.
https://icc.journals.pnu.ac.ir/article_4234_73f9858c522e4ed8ec70859d4e6beaad.pdf
2019-01-01
63
70
10.30473/icc.2019.4234
styrene
butyl acrylate, emulsion polymerization
nanocomposites
montmorillonite
Mohsen
Oftadeh
m_oftadeh@pnu.ac.ir
1
Chemistry Department, Payame Noor University, 19395-4697 Tehran, Iran
LEAD_AUTHOR
Fahad
Hajati
farhadhajati@gmail.com
2
Department of Chemistry, Islamic Azad University, Shahreza Branch, P.O.BOX 311-86145, Shahreza, Isfahan, Iran.
AUTHOR
Mortaza
Jamshidi
ezad130@gmail.com
3
Department of Chemistry, Islamic Azad University, Shahreza Branch, P.O.BOX 311-86145, Shahreza, Isfahan, Iran.
AUTHOR
Hamid
Javaherian Naghash
javaherian@iaush.ac.ir
4
Department of Chemistry, Islamic Azad University, Shahreza Branch, P.O.BOX 311-86145, Shahreza, Isfahan, Iran.
AUTHOR
[1] G. Xua, C. Denga, L. Xinga, J. Hu, , Int. J. Polymer. Mater., 2013, 62, 488-492.
1
[2] G. Fei, H. Wang, X. Li, J. Mou, Polym. Bull., 2011, 67, 1017-1028.
2
[3] B.Q. Jiang, S.F. Hu, J.G. Zou, X.Y. Yu, Appl. Chem. Ind., 2011, 168-170, 2065-2068.
3
[4] X.Z. Zhang, P. Wang, L. Liu, J.B. Xiong, Adv. Mater. Res., 2012, 535-537, 2491-2494.
4
[5] E. Pouget, J. Tonnar, P. Lucas, P. Lacroix-Desmazes, F. Ganachaud, B. Boutevin, Chem. Rev., 2010, 110, 1233-1277.
5
[6] H. Javaherian Naghash, F. Hajati, J. App. Polym. Sci., 2012, 123, 1227-1237.
6
[7] B.A. Bhanvase, D.V. Pinjari, P.R. Gogate, S.H. Sonawane, A.B. Pandit, Chem. Eng. J., 2012, 181-182, 770-778.
7
[8] H. Javaherian Naghash, R. Mohammadrahimpanah, Prog. Org. Coat., 2011, 70, 32-38.
8
[9] R.P. Moraes, A.M. Santos, P.C. Oliveira, F.C.T. Souza, M.d. Amaral, T.S. Valera, N.R. Demarquette, Macromol. Symp., 2006, 245-246, 106-115.
9
[10] S.S. Ray, M. Okamoto, Prog. Polym. Sci., 2003, 28, 1539-1641.
10
[11] J.W. Gilman, W.H. Awad, R.D. Davis, J. Shields, R.H. HarrisJr, C. Davis, A.B. Morgan, T.E. Sutto, J. Callahan, P.C. Trulove, H.C. DeLong, Chem. Mater., 2002, 14, 3776-3785.
11
[12] M. Zanetti, P. Bracco, L. Costa, Thermal degradation behaviour of PE/clay nanocomposites, Polym. Degrad. Stabil., 2004, 85, 657-665.
12
[13] J.W. Gilman, Appl. Clay Sci., 1999, 15, 31–49.
13
[14] A. Leszczynska, J. Njuguna, K. Pielichowski, J.R. Banerjee, ThermochimActa, 2007, 454, 1-22.
14
[15] E.P. Giannelis, Appl. Organomet. Chem., 1998, 12, 675-680.
15
[16] Y. Tang, Y. Hu, S. Wang, Z. Gui, Z. Chen, W. Fan, Polym. Degrad. Stabil., 2002, 78, 555-561.
16
[17] S. Wang, Y. Hu, R. Zong, Y. Tang, Z. Chen, W. Fan, Appl. Clay. Sci., 2004, 25, 49-55.
17
[18] L. Song, Y. Hu, Z. Lin, S. Xuan, S. Wang, Z. Chen, Polym. Degrad. Stabil., 2004, 86, 535-540.
18
[19] H. Javaherian Naghash, A. Karimzadeh, A.R. Massah, J. Appl. Polym. Sci., 2009, 112, 1037-1044.
19
[20] X. Yuan, X. Li, E. Zhu, J. Hu, S. Cao, W. Sheng, J. Carbohydr. Polym., 2010, 79, 373-379.
20
[21] A. Dabbagh, J.L. Ford, M.H. Rubinstein, J.E. Hogan, Int. J. Pharm., 1996, 140, 85–95.
21
[22] S. Inukai, T. Tanma, S. Orihara, M. Konno, Chem. Eng. Res. Des., 2001, 79, 901-905.
22
[23] X. Feng, A. Zhong, D. Chen, J. Appl. Polym. Sci., 2006, 101, 3963-3970.
23
ORIGINAL_ARTICLE
Synthesis, characterization and spectroscopic properties of new azo dyes derived from aniline derivatives based on acetylacetone and azo-metal (II) complexes and singular value decomposition (SVD) investigation
Four new azo-dyes, 3-phenyl azopentane-2,4-dion (LA), 3-(4-nitro phenyl azo)-pentane-2,4-dion (LP), 3-(2-nitro phenyl azo)-pentane-2,4-dion (LO) and 4-(1-acetyle-2-oxo-propyl azo)-benzene sulfonate sodium (LS), were synthesized from, aniline, 4-nitroaniline, 2-nitroaniline and sulfanilic acid with acetylacetone, respectively. Reaction of these new dyes with acetate salts of copper(II), nickel(II) and cobalt(II) in molar ratios of 1:2 were carried out to produce azo metal (II) complexes with the general stoichiometry; CuL2, CoL2 and NiL3 in complexes. Structure of azo dyes was characterized using FT-IR,1H NMR,13C NMR, UV-Visible and also the corresponding metal (II) complex were characterized by FT IR, UV-Visible and CHN and XRD analysis techniques. Elemental analysis and spectral data indicated that the dye as a ligand with two teeth, N and O, acts as a bidentate ligand. Differences in absorption maxima of azo ligands compared to those corresponding complexes were also studied. Also, in this work, singular value decomposition (SVD) as a chemometric method was used to determine the Cu(II), Co(II) and Ni(II) complexes with the mentioned ligands in methanol by UV-Vis spectrophotometry. SVD method confirmed the formation of CuL2, CoL2 and NiL3 complexes.
https://icc.journals.pnu.ac.ir/article_3951_f1ed75301ccbf498182b35a4e82a870f.pdf
2019-01-01
71
89
10.30473/icc.2019.3951
azo dye
sulfanilic acid
acetylacetone
bifurcated intramolecular H-bond
azo-metal (II) complex
Nader
Noroozi Pesyan
n.noroozi@urmia.ac.ir
1
Faculty of Chemistry, Urmia University, 57159, Urmia, Iran
LEAD_AUTHOR
Vali
Gholsanamloo
v.golsanamlu@urmia.ac.ir
2
Faculty of Chemistry, Urmia University, 57159,Urmia, Iran
AUTHOR
Maryam
Moradi Par
mahdam4@gmail.com
3
Faculty of Chemistry, Urmia University, 57159,Urmia, Iran
AUTHOR
Hamid
Rashidnejad
herr.hamid.rashidnejad@gmail.com
4
Faculty of Chemistry, Urmia University, 57159,Urmia, Iran
AUTHOR
Ali
Gharib
organiccatalyst2008@gmail.com
5
Department of Chemistry, Islamic Azad University, Mashhad, Iran
AUTHOR
Kamelia
Nejati
nejati_k@yahoo.com
6
Department of Chemistry, Payame Noor University, PO.BOX 19395-3697 Tehran, Iran
AUTHOR
[1] J. Koh, A.J. Greaves, Dyes Pigments, 2001, 50, 13-19.
1
[2] N. Sekar, Colourage, 1999, 46, 63-65.
2
[3] H.E. Katz, K.D. Singer, J.E. Sohn, C.W. Dirk, L.A. King, H.M. Gordon, J. Am. Chem. Soc, 1987, 109, 6561-6563.
3
[4] T. Abe, S. Mano, Y. Yamada, A. Tomotake, J. Imag. Sci. Technol, 1999, 43, 339-344.
4
[5] T. Chino, M. Yamada, JP 2001220519, 2002.
5
[6] S. Wang, S. Shen, H. Xu, Dyes Pigments, 2000, 44, 195-198.
6
[7] K. Maho, T. Shintaro, K. Yutaka, W. Kazuo, N. Toshiyuki, T. Mosahiko, Jpn. J. Appl. Phys, 2003, 42, 1068-1078.
7
[8] D.W. Rangnekar, V.R. Kanetkar, J.V. Malanker, G.S. Shankarling, Indian J. Fibre Text. Res, 1999, 24, 142-144.
8
[9] G. Hallas, J.H. Choi, Dyes Pigments, 1999, 40, 119-129.
9
[10] P. Gregory, D.R. Waring, G. Hallos, The chemistry and application of dyes, London, Plenum Press, 1990, 18-20.
10
[11] S.S. Kondil, Transition Metal. Chem, 1998, 23, 461-464.
11
[12] J.W. Daniel, Toxicol. Appl. Pharmacol, 1962, 4, 572-594.
12
[13] O.E. Woisetsclager, K. Sunkel, W. Weigand, W. Beck, J. Organometal. Chem, 1999, 584, 122-130.
13
[14] J.A.C. Broekaert, Anal. Chim. Acta, 1981, 124, 421-425.
14
[15] A.L. Amin, T.Y. Mohammed, Talanta, 2001, 54, 611-620.
15
[16] K.T. Chung, Mutat. Res, 1983, 114, 269-281.
16
[17] K.T. Chung, J. Environ. Sci. Health, Part C: Environ. Carcin. Ecotoxicol. Rev, 2000, 18, 51-74.
17
[18] A. Gottlieb, C. Shaw, A. Smith, A. Wheatley, S. Forsythe, Biotechnol, 2003, 101, 49-56.
18
[19] M.A. Brown, S.C. Vito, Critic. Rev. Environ. Sci. Tech, 1993, 23, 249-324.
19
[20] T. Deb, D. Choudhury, P. Sarathi Guina, M.B. Sahaa, Chemico-Biolog. Interact, 2001, 189, 206-2014.
20
[21] R. Gup, E. Giziroglu, B. Kırkan, Dyes Pigments, 2007, 73, 40-46.
21
[22] A. Lyčka, D. Luštinec, J. Holeček, M. Nádvorník, M. Holčapek, Dyes Pigments, 2001, 50, 203–209.
22
[23] K. Nejati, Z. Rezvani, B. Massoumi, Dyes Pigments, 2007, 75, 653-657.
23
[24] S. Norman, M. Maeder, Critical Rev. Anal. Chem, 2006, 36, 199-209.
24
[25] N. Samadi, M. Salamati, Bull. Chem. Soc. Ethiop, 2014, 28, 373-382.
25
[26] W.A. Shehab, Z. Al-qudah, Int. J. Computer Networks Commun. (IJCNC), 2017, 9, 13-21.
26
[27] R.I. Shrager, Chemometr. Intell. Lab. Syst, 1986, 1, 59-70
27
[28] N. Kumar, A. Bansal, G.S. Sarma, R.K. Rawal, Talanta, 2014, 123, 186–199.
28
[29] M. Bahram, N. Noroozi Pesyan, A. Naseri, M. Tasbihforosh, Turk. J. Chem, 2011, 35, 255-264.
29
[30] F. Huang, Y. Wua, D. Gu, F. Gan, Mater. Lett, 2004, 58, 2461-2465.
30
[31] M.R. Zamanloo, A.N. Shamkhali, M. Alizadeh, Y. Mansoori, Dyes Pigments, 2012, 95, 587-599.
31
[32] W.A. Lees, A. Burawoy, Tetrahedron, 1963, 19, 373-498.
32
[33] M.C. Morris, H.F. McMurdie, E.H. Evans, B. Paretzkin, H.S. Parker, N.C. Panagiotopoulos, C.R. Hubbard, “Standard X-ray Diffraction Powder Patterns Section 18 - Data for 58 Substances” International Centre for Diffraction Data, National Measurement Laboratory, National Bureau of Standards, Washington, DC 20234, 1981.
33