eng
Iranian chemical communication
2423-4958
2345-4806
2018-04-01
6
Issue 2, pp. 109-217, Serial No. 19
109
113
3360
Ultrasound assisted oxidation of various alcohols to corresponding aldehydes by using Al2O3 as catalyst
Sadegh Rahmati
rahmati61@yahoo.com
1
Ardeshir Khazaei
khazaei_1326@yahoo.com
2
Maryam Golbaghi
3
Mohammad Panahimehr
4
payame noor university
Faculty of Chemistry, Bu-Ali Sina University, P.O. BOX 651783868, Hamedan, Iran
Department of Chemistry, Payame Noor University (PNU), P.O. BOX 19395-3697 Tehran, Iran
Young Researchers and Elite Club, Gachsaran Branch, Islamic Azad University, Gachsaran, Iran
A convenient approach for oxidation of structurally diverse alcohols has been developed using KMnO4 as oxidant agent in the presence of a catalytic amount of Al2O3 in aqueous acetonitrile. In this method various alcohols generally afforded the corresponding carbonyl compounds directly in good to high yield under ultrasound irradiation conditions. It shows that this kind of catalysis system is very active, selective and suitable for oxidation of benzylic alcohols. Furthermore, all products were obtained through a simple filtration and washed with solvent, and there was no need for column chromatography. All products have been characterized by IR and 1HNMR spectral data.
https://icc.journals.pnu.ac.ir/article_3360_bdad1f309b83721d400502066f73154a.pdf
Oxidation
alcohols
potassium permanganate
ultrasound
eng
Iranian chemical communication
2423-4958
2345-4806
2018-04-01
6
Issue 2, pp. 109-217, Serial No. 19
114
124
4573
Petra, osiris and molinspiration: A computational bioinformatic platform for experimental in vitro antibacterial activity of annulated uracil derivatives
Ajmal Bhat
bhatajmal@gmail.com
1
Department of Natural Science, S.B.B.S.University, Jalandhar Punjab-144030 (India)
Annulated pyrano[2,3-d]pyrimidine/pyrano[2,3-d]uracil derivatives were synthesized using aromatic aldehydes, active methylene compounds and barbituric acid in presence of dibutylamine (DBA) catalyst in ethanol as solvent. The different substituents on phenyl ring in the fused pyrano uracil skeleton showed productive influence on its antimicrobial activity against some gram positive and gram negative bacteria like Pseudomonas aureus, E. coli, Staphylococcus aureus, Klebsiella pneumonia and Bacillus cereus. Antibacterial screening revealed that the presence of heteroaryl, cyano and amino groups on uracil skeleton increases its penetrating power on bacterial cell wall and product becomes more biologically energetic. The antimicrobial activity results showed some definite and interesting facts about the structure activity relationship (SAR) of synthesized molecules.
https://icc.journals.pnu.ac.ir/article_4573_319492ba33c5dac4efaf3b5d236cc229.pdf
Annulated uracils
structural dependent biological activity
gram positive
gram negative bacteria
pharmacophore sites
eng
Iranian chemical communication
2423-4958
2345-4806
2018-04-01
6
Issue 2, pp. 109-217, Serial No. 19
125
133
3590
Efficient one-pot synthesis of 6-amino-4-aryl-5-cyano-2-methyl-4H-pyran-3-carboxylates catalyzed by nano MgO in water
Maryam Sojoudi
mas_polychem@yahoo.com
1
Masoud Mokhtary
mmokhtary@iaurasht.ac.ir
2
Department of Chemistry, Rasht Branch, Islamic Azad University, Rasht, Iran
Islamic Azad University, Rasht branch, Iran
Water is a versatile solvent in many ways, and in this sense performing organic reactions in this medium is now of great interest. The one-pot reaction of ethyl acetoacetate or benzyl acetoacetate, with benzaldehydes and malononitrile to provide some novel 6-amino-4-aryl-5-cyano-2-methyl-4H-pyran-3-carboxylates has been performed over nano MgO with high performance in water as a green solvent at 80 °C. The nanocrystalline MgO catalyst was characterized via X-ray diffraction (XRD), transmission electron microscopy (TEM) and BET analysis. This method offers considerable improvements for the synthesis of 6-amino-4-aryl-5-cyano-2-methyl-4H-pyran-3-carboxylates with concern to the yield of products, facility in operation, and green aspects without using of toxic catalysts and solvents.
https://icc.journals.pnu.ac.ir/article_3590_e5156271839295e71f8f98f4ba28f7e8.pdf
6-Amino-5-cyano-4H-pyrans
malononitrile
nano MgO
one-pot reaction
Water
eng
Iranian chemical communication
2423-4958
2345-4806
2018-04-01
6
Issue 2, pp. 109-217, Serial No. 19
134
142
3607
One-pot multicomponent click synthesis of some novel 1,4-disubstituted-1H-1,2,3-triazoles from alkenes
Mosadegh Keshavarz
chem.mosadegh@gmail.com
1
Department of Gas and Petroleum Yasouj University, Yasouj 75918–74831, Iran
A facile and one-pot multicomponent synthesis of novel 1,4-disubstituted-1H-1,2,3-triazoles from alkenes at room temperature is reported. At the first step, in the presence of I2/NaN3 reagents, various alkenes were converted to the corresponding azido iodides and in the next step, the reaction of these compounds with phenylacetylene in the presence of catalytic amount of sodium ascorbate/ CuSO4 afforded regioselective synthesis of 1,4-disubstituted-1H-1,2,3-triazoles in short times and at good to high yields. This greenapproach has several advantages such as short reaction times, clean reaction profiles, and simple experimental and workupprocedures. All the products were fully characterized by 1HNMR, 13CNMR, IR and CHN analysis
https://icc.journals.pnu.ac.ir/article_3607_9c4c9eb873175b9123003b46cf8520d1.pdf
Click chemistry
styrene
regioselective
sodium azide
triazole
azido iodination
eng
Iranian chemical communication
2423-4958
2345-4806
2018-04-01
6
Issue 2, pp. 109-217, Serial No. 19
143
147
3608
Isolation and identification macrocyclic spermine alkaloid(protoverbine) from verbascum speciosum.
Majid Halimi
majid_halimi@pnu.ac.ir
1
Malihe Nasrabadi
malnasr2000@yahoo.com
2
Chemistry Department, Payame Noor University, 19395-4697 Tehran, I. R. of Iran
Chemistry Department, Payame Noor University, 19395-4697 Tehran, I. R. of Iran
The 17-membered macrocyclic spermine alkaloid protoverbine (8-phenyl-1,5,9,13-tetra azacycloheptadecan-6-one) was isolated From the aerial part of verbascum speciosum. The natural polyamines are ubiquitous bases reported to have several important functions in animals, plants and microorganisms. They are involved in processes of transcription and translation in protein synthesis and influence growth and development (cell division, differentiation, embryogenensis, etc.). In plants their involvement in organ development, flowering, fruit ripening, senescence and stress responses is reported. The structure of the protoverbine established by a study of their spectral such as 1HNMR,13C-NMR, IR, ESI-MS analyses and chemical properties. To the best of our knowledge, this is the first report of protoverbine from this species.
https://icc.journals.pnu.ac.ir/article_3608_005472786c89425b1814fd7cd951a167.pdf
verbascum speciosum
alkaloid
separation
protoverbine
macrocyclic spermine
MPLC
eng
Iranian chemical communication
2423-4958
2345-4806
2018-04-01
6
Issue 2, pp. 109-217, Serial No. 19
148
159
3609
Adsorption of Pb(II) by activated carbon prepared from Melia azedarach fruit: Equilibrium and thermodynamics
Fatemeh Sabermahani
fatemehsaber2003@yahoo.com
1
Nosrat Madadi Mahani
nmmadady@gmail.com
2
Neda Pourgholamrezazadeh
gholamrezayineda@gmail.com
3
Payeme Noor University of Kerman
Department of Chemistry, Payame Noor University of Kerman
Department of Chemistry, Payame Noor University of Kerman
In this work, a low-cost activated carbon as well as non-hazardous material, with high adsorption capacity, was prepared from Melia azedarach fruit (MF) by ZnCl2 activation for the removal of Pb(II) toxic metal from aqueous solutions. The microstructure of the activated carbon was observed by Scanning Electron Microscopy (SEM). Batch experiments have been performed as a function of pH, contact time, dose of sorbent, initial Pb(II) concentration, temperature and strength ionic. It was found that the adsorption process was very quick and the equilibrium attained within 10 min. The maximum adsorption capacity for Pb(II) using Langmuir isotherm was 111.11 mg g-1. Thermodynamic study indicated that the Pb(II) adsorption was feasible, spontaneous, and endothermic. The results show that the produced activated carbon from Melia azedarach fruit is an efficient and cost-effective adsorbent for removing Pb(II).
https://icc.journals.pnu.ac.ir/article_3609_d5e29c202fb0d0c5a942bf95a532c701.pdf
Chemically prepared activated carbon
lead
Melia azedarach fruit
removal
eng
Iranian chemical communication
2423-4958
2345-4806
2018-04-01
6
Issue 2, pp. 109-217, Serial No. 19
160
168
4572
Investigation of structural, morphological and dynamic mechanical properties of unvulcanized PDMS/silica compound
Liu Jiesheng
ljs628@whpu.edu.cn
1
Li Faping
lfp@163.com
2
Xing Shanshan
xss@126.com
3
He Xiang
hx@whpu.edu.cn
4
Wuhan Polytechnic University
Wuhan Polytechnic University
Wuhan Polytechnic University
Wuhan Polytechnic University
In this study, the interaction between the silica filler and polydimethylsiloxanes (PDMS) was investigated from the aspects of the bound rubber and morphological characterization. With special attention to the dynamic properties, the dynamic test was conducted by dynamic shear rheometer. The results show that the modified fillers disperse uniformly within PDMS matrix without aggregation and connect closely with the matrix than that of the unmodified fillers. Surface modification of filler increases the bound rubber content. The increase in silica loading leads to an increase in the silica-silica interaction and a decrease in filler-rubber interaction, which results in the aggregation of fillers and the increase of the bound rubber content. It was apparent that storage modulus, loss modulus and tanδ of unvulcanized PDMS/filler compounds filled with treated silica filler were lower than that of the untreated silica system. Moreover, the tanδ decreases with increasing silica loading.
https://icc.journals.pnu.ac.ir/article_4572_79548517f4103d01d469a93d08a3def4.pdf
PDMS
silica
modification
bound rubber
dynamic properties
eng
Iranian chemical communication
2423-4958
2345-4806
2018-04-01
6
Issue 2, pp. 109-217, Serial No. 19
169
179
3610
The zinc chromium ferrite magnetic nanoparticles ZnCrFeO4: An efficient catalyst for acetylation of alcohols, phenols and amines under solvent-free conditions
Nahid Rasouli
n.rasooli55@yahoo.com
1
Maryam Movahedi
maria_movahedi@yahoo.com
2
Elaheh Aghabeikzadeh Naeini
el.aghabeikzadeh@yahoo.com
3
Payame Noor University
Payame Noor University
Payame Noor University
In this study, the zinc chromium ferrite magnetic nanoparticles ZnCrFeO4 are synthesized via sol-gel method and characterized by X-ray diffraction (XRD) analysis, Fourier transform infrared spectroscopy (FT-IR) and scanning electron microscopy (SEM). The XRD analysis showed that ZnCrFeO4 has single-phase cubic structure. The synthesized ZnCrFeO4 has been used as an efficient catalyst for acetylation of alcohols, phenols and amines with acetic anhydride under mild and solvent free conditions. The ZnCrFeO4 catalyst can be readily removed using an external magnet and no obvious loss of activity was observed after three consecutive runs. Also, the effect of time, amount and type of catalyst were investigated.
https://icc.journals.pnu.ac.ir/article_3610_ec4d7cc30e85539651b063803f2a6fee.pdf
Acetylation
catalyst
magnetic
solvent free
eng
Iranian chemical communication
2423-4958
2345-4806
2018-04-01
6
Issue 2, pp. 109-217, Serial No. 19
180
191
3616
Mn (III) salen complex supported on graphene oxide nanosheets as a highly selective and recoverable catalyst for the oxidation of sulfides
Ali Allahresani
a_allahresani@birjand.ac.ir
1
Department of Chemistry,Faculty of Sciences, University of Birjand, P.O. BOX 97175-615, Birjand, Iran
In this study, Mn (III) salen complex was synthesized and immobilized onto the graphene oxide, which is modified by 3-chloropropyltrimethoxy silane. Heterogeneous catalyst was characterized by X-ray diffraction, transmission electron microscopy, thermogravimetric analysis, fourier transform infrared spectra, nitrogen adsorption−desorption isotherm and atomic absorption spectroscopy. The catalytic activity of heterogeneous Mn (III) salen complex and comparison with its homogeneous analogue was studied for green oxidation of sulfide derivatives using aqueous 30% H2O2 as an oxidant in water media. The results showed that heterogeneous catalyst was highly efficient in this reaction and corresponding products were obtained in good to excellent yields. The advantages of this catalyst include short reaction times, no side reactions, easy and simple work up, mild reaction conditions and excellent selectivity. The heterogeneous nanocatalyst was reused for several runs without significant loss in activity and selectivity.
https://icc.journals.pnu.ac.ir/article_3616_62976cdf5d882e61d7269fdb62462965.pdf
Mn (III) salen complex
sulfides
Oxidation
graphene oxide
eng
Iranian chemical communication
2423-4958
2345-4806
2018-04-01
6
Issue 2, pp. 109-217, Serial No. 19
192
208
3617
Design, preparation and characterization of a novel BiFeO3/CuWO4 heterojunction catalyst for one-pot synthesis of trisubstituted imidazoles
Hamed Ramezanalizadeh
hramzanalizadeh@gmail.com
1
Young Researchers and Elites Club, Roodsar branch, Islamic azad university, Roodsar, Islamic replic of iran
In this work a novel heterojunction catalyst have been synthesized and employed as a highly efficient catalyst for one-pot synthesis of substituted imidazoles. Analytical methods including Fourier transform infrared (FT-IR), diffuse reflectance spectroscopy (DRS), X-ray diffraction (XRD), Energy- dispersive X-ray spectroscopy (EDX), Scanning electron microscopy (SEM) and Vibrating Sample Magnometer (VSM) were used for the catalyst characterization. Moreover, the catalyst was also recovered and reused five times without remarkable decrease in its catalytic activity. Compared to the classical methodologies, this method illustrated significant advantages including low loading of the catalyst, short reaction times, high to excellent yields, easy separation and purification of the products.
https://icc.journals.pnu.ac.ir/article_3617_217f77ea38a3b5a2067391054682700a.pdf
BiFeO3/CuWO4
Heterogeneous catalyst
trisubstituted imidazoles
solvent free
magnetic BiFeO3
eng
Iranian chemical communication
2423-4958
2345-4806
2018-04-01
6
Issue 2, pp. 109-217, Serial No. 19
209
217
3619
Volumetric properties of high temperature, high pressure supercritical fluids from improved van der Waals equation of state
Ahmad Razavizadeh
razavi_zadeh@yahoo.com
1
Fahimeh Alirezapoor
falirezapoor@gmail.com
2
Department of Chemistry, Payame Noor University, P. O. BOX 19395-3697 Tehran, Iran
Department of Chemistry, Payame Noor University, P. O. BOX 19395-3697 Tehran, Iran
In the present work, a modified equation of state has been presented for the calculation of volumetric properties of supercritical fluids. The equation of state is van der Waals basis with temperature and density-dependent parameters. This equation of state has been applied for predicting the volumetric properties of fluids. The densities of fluids were calculated from the new equation of state at different temperatures and pressures in the supercritical region. The predicted densities have been compared with those obtained from the experiment, over a broad range of pressure. It is found that the new equation of state yields excellent results in comparison with 1894 experimental data points with overall average absolute deviation percent (AAD %) of 0.98% in density for the pure studied compound. The studied fluids are: CH4, C2H6, C3H8, C4H10, C5H12, C6H14, C7H16, C8H18, C10H22, C12H26, C2H4, C6H6, C6H12, C7H8, O2, N2 and CO2.
https://icc.journals.pnu.ac.ir/article_3619_a65f651263e11a4e19d279807ddfc73b.pdf
Equation of state
supercritical
density
high temperature
high pressure
van der Waals