eng
Iranian chemical communication
2423-4958
2345-4806
2016-07-01
4
Issue 3, pp. 236-358, Serial No. 12
236
244
2113
Physico-chemical features of Aqueous extract of acanthophyllum laxiusculum roots from natural steppe habitats of Iran: Evaluating surface activity and thermal behavior of partially purified extract
Hajar Soltaninejad
h_soltaninejad87@yahoo.com
1
Zahra Madadi
negar.madadi@gmail.com
2
Tayebe Bagheri Lotfabad
bagheril@nigeb.ac.ir
3
Atefeh Pirani
atefeh.pirani@gmail.com
4
Negissa Ebadipour
nakisa_pl@yahoo.com
5
Department of Energy and Environmental Biotechnology, Institute of Industrial and Environmental Biotechnology(IIEB), National Institute of Genetic Engineering and Biotechnology (NIGEB), P.O. Box 14965/161, Tehran, Iran
Department of Energy and Environmental Biotechnology, Institute of Industrial and Environmental Biotechnology(IIEB), National Institute of Genetic Engineering and Biotechnology (NIGEB), P.O. Box 14965/161, Tehran, Iran
Department of Energy and Environmental Biotechnology, Institute of Industrial and Environmental Biotechnology(IIEB), National Institute of Genetic Engineering and Biotechnology (NIGEB), P.O. Box 14965/161, Tehran, Iran
Traditional Medicine and Materia Medica Research Center, Shahid Beheshti University of Medical Sciences, Tehran, Iran.
Department of Energy and Environmental Biotechnology, Institute of Industrial and Environmental Biotechnology(IIEB), National Institute of Genetic Engineering and Biotechnology (NIGEB), P.O. Box 14965/161, Tehran, Iran
Acanthophyllum laxiusculum is one of the most widely distributed species of the genus in Iran that flourishes in steppe and mountainous regions of the country. In the present study, water-soluble content of A. laxiusculum roots was extracted by boiling water and further successively purified partially by a defined solvent system. Surface tension measurements revealed the ability of plant extract to decrease the surface tension of water from 72 to 38mN/m with a critical micelle concentration (CMC) of 87.3 mg/l. The partially purified natural extract (PPNE) exhibited 65% emulsification activity (E24) on kerosene. A combination of UV–VIS spectroscopy and Fourier transform infrared spectroscopy (FTIR) demonstrated the presence of saponin compounds in PPNE. Moreover, thermostability of PPNE was evaluated by thermal gravimetric analysis (TG) and differential thermal analysis (DTA). TG-DTG analysis showed a complex three-stage thermal degradation mechanism and this conclusion was also supported by the DTA spectrum.
https://icc.journals.pnu.ac.ir/article_2113_eb627be368422e0ef64e0adbe290a4e3.pdf
Acanthophyllum laxiusculum
saponin
plant
critical micelle concentration
eng
Iranian chemical communication
2423-4958
2345-4806
2016-07-01
4
Issue 3, pp. 236-358, Serial No. 12
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2114
A green and eco-friendly method for the synthesis of xanthene derivatives using cellulose sulfuric acid under solvent-free conditions
Seyyedeh Cobra Azimi
cobra.azimi@gmail.com
1
Esmayeel Abbaspour-Gilandeh
2
Islamic Azad University, Rasht, Iran
Islamic Azad University, Ardabil, Iran
A green and convenient method for the synthesis of 14-aryl-14H-dibenzo[a,i]xanthene-8,13-diones and spiro[dibenzo[a,i]-xanthene-14,3'-indoline]-2',8,13-triones in the presence of a catalytic amount of cellulose sulfuric acid (CSA) as an efficient biopolymer-based catalyst under solvent-free conditions at 100 °C is described. The condensation reactions of β-naphtol, 2-hydroxynaphthalene-1,4-dione with aldehydes or isatins to afford the corresponding xanthenes in good to excellent yields. To the best of our knowledge, it is the first example of a multicomponent reaction to the synthesis of these compounds using cellulose sulfuric acid. The present approach offers several advantages such as shorter reaction times, simple work-up, excellent yields, non-toxicity of the catalyst, and solvent-free conditions. Moreover, cellulose sulfuric acid is successfully reused for four cycles without significant less of activity.
https://icc.journals.pnu.ac.ir/article_2114_a646e9fc09ce4c04ee20060cdc661819.pdf
Xanthenes
cellulose sulfuric acid
2-hydroxynaphthalene-1,4-dione
β-naphtol
solvent-free
eng
Iranian chemical communication
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2345-4806
2016-07-01
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Issue 3, pp. 236-358, Serial No. 12
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2198
Application of carbon ceramic modified electrode with prussian blue for electrocatalytic oxidation of nitrite ion
Sohrab Ershad
sohrabsd@yahoo.com
1
Noshin Safarzadeh
2
Hamzeh Akhondi-Yamchi
3
marand
Department of Chemistry, Payame Noor University, P.O. BOX 19395-4697 Tehran, Iran
Department of Chemistry, Payame Noor University, P.O. BOX 19395-4697 Tehran, Iran
A novel chemically modified electrode containing Prussian blue complex was achieved on the surface of glass carbon electrode by sol-gel technique. The electrochemical behavior of modified electrode was characterized by cyclic voltammetry in detail. The film electrode obtained was very stable and exhibited electrocatalytic response for oxidation of nitrite. Results showed at bare GC electrode, a small oxidation peak current was observed at about 740 mV and a well-formed sharp catalytic oxidation peak at about 600 mV was observed at Prussian blue complex modified electrode. The transfer coefficient (α) for electrocatalytic oxidation of nitrite and the diffusion coefficient of this substance under the experimental conditions were also investigated.
https://icc.journals.pnu.ac.ir/article_2198_5f88e51251aa261b74c267d38694e9eb.pdf
Prussian blue complex
cyclic voltammetry
nitrite
electrocatalytic oxidation
eng
Iranian chemical communication
2423-4958
2345-4806
2016-07-01
4
Issue 3, pp. 236-358, Serial No. 12
265
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2199
Solid state synthesis of NiO nanoparticles from [(1,2-bis(2-formyl-3-methoxyphenyl)propane)nickel(II)] chloride
Aliakbar Dehno Khalaji
ad.khalaji@gu.ac.ir
1
Fatemeh Gharib
f.gharib@yahoo.com
2
Department of Chemistry, Faculty of Science, Golestan University, Gorgan, Iran
Department of Chemistry, Faculty of Science, Golestan University, Gorgan, Iran
In this paper, nickel oxide (NiO) nanoparticles have been prepared by solid state thermal decomposition of an acyclic nickel(II) complex (1,2-bis(2-formyl-3-methoxyphenyl)propane)nickel(II) chloride, [NiL]Cl2, in an electrical furnace at optimal temperature, 450 ºC for 3.5 h. The nickel(II) complex is obtained via solid state synthesis using nickel(II) chloride and tetradentate O4 acyclic ligand 1,2-bis(2-formyl-3-methoxyphenyl)propane. The structure and morphology of NiO nanoparticles are characterized by Fourier transform infrared spectroscopy (FT-IR), powder X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). XRD and TEM analysis show that NiO nanoparticles have pure and cubic phase with the average size of 5-10 nm.
https://icc.journals.pnu.ac.ir/article_2199_9125d68b021cd0f32620b5843114a0b5.pdf
Nickel oxide
nanoparticles
Solid state
nickel(II) complex
eng
Iranian chemical communication
2423-4958
2345-4806
2016-07-01
4
Issue 3, pp. 236-358, Serial No. 12
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2200
An efficient solvent-free synthesis of 1,8-dioxo-octahydroxanthenes by using Fe2(SO4)3.7H2O as catalyst
Reyhaneh Khoeiniha
rkhoeiniha@yahoo.com
1
Ali Ezabadi
aliezabadi@yahoo.com
2
Abolfazl Olyaei
olyaei_a@pnu.ac.ir
3
Department of Chemistry, Faculty of Sciences, Central Tehran Branch, Islamic Azad University, P.O. BOX 14676-86831,Tehran, Iran
Department of Chemistry, Faculty of Sciences, Central Tehran Branch, Islamic Azad University, P.O. BOX 14676-86831,Tehran, Iran
Department of Chemistry, Payame Noor University, PO BOX 19395-3697, Tehran, Iran.
A facile and efficient protocol for the synthesis of 1,8-dioxo-octahydroxanthenes has been developed by one-pot Knoevenagel condensation, Michael addition and cyclodehydration reaction of dimedone (active methylene carbonyl compound) with aromatic aldehydes in the presence of Iron (III) sulfate hydrate as a solid acidic catalyst under solvent-free conditions. Various aromatic aldehydes were utilized in the reaction and in all situations the desired product were synthesized successfully. The present methodology is cost-effective in addition to other advantages like high yields of products in shorter reaction time and simple workup procedure. The non toxicity and easy availability of the catalyst makes this protocol efficient and environmentally benign.
https://icc.journals.pnu.ac.ir/article_2200_29b064cc917ce9bf2ab18dcb4f08d8c9.pdf
xanthene
Iron (III) sulfate hydrate
dimedone
aromatic aldehyde
eng
Iranian chemical communication
2423-4958
2345-4806
2016-07-01
4
Issue 3, pp. 236-358, Serial No. 12
283
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2201
Mn(II) salen complex immobilized on nano silicagel as a recyclable heterogeneous catalyst for oxidation of alcohols to their corresponding carbonyl compounds
Mohammad Ali Nasseri
manaseri@birjand.ac.ir
1
Batol Zakerinasab
bzakerinasab@birjand.ac.ir
2
Sayyde Kamayestani
s.kamayestani@yahoo.com
3
Department of Chemistry, College of Sciences, University of Birjand, Birjand 97175-615, Iran
Department of Chemistry, College of Sciences, University of Birjand, Birjand 97175-615, Iran
Department of Chemistry, College of Sciences, University of Birjand, Birjand 97175-615, Iran
Mn(II) salen complex immobilized on nano silicagel was prepared by incorporating Mn(II) salen complex into a nanosilica matrix and characterized by TGA, XRD, atomic absorption spectroscopy and was successfully applied as catalyst for the oxidation of alcohols. Oxidation of a series of alcohols in acetonitrile over immobilized Mn(II) salen complex using tetrabutylammonium peroxymonosulfate (TBAO) as oxidant were resulted to the corresponding carbonyl compounds selectively in moderate to high yields. It is noteworthy that the aldehydes do not undergo further oxdation to carboxylic acids. The yields of aromatic alcohols are higher than those of alcohols with aliphatic groups. The catalyst has been reused several times, without observable loss of its activity and selectivity.
https://icc.journals.pnu.ac.ir/article_2201_8629bfde5f744a002b794bae04a0ee0e.pdf
Immobilized Mn salen
oxidation of alcohols
nano silicagel
eng
Iranian chemical communication
2423-4958
2345-4806
2016-07-01
4
Issue 3, pp. 236-358, Serial No. 12
295
308
2202
(Carboxy-3-oxopropylamino)-3-propylsilylcellulose as a novel organocatalyst for the synthesis of coumarin derivatives under solvent-free conditions
Mehri Salimi
msalimi@birjand.ac.ir
1
Department of Chemistry, College of Sciences, University of Birjand, P. O. Box 97175-615, Birjand, Iran
In this research, (Carboxy-3-oxopropylamino)-3-propylsilylcellulose (COPAPSC) as an organocatalyst, has been synthesized by grafting of succinic anhydride on the NH2-modified cellulose (cellulose functionalized with 3- aminopropyltriethoxysilane). The –CO2H group-functionalized cellulose (COPAPSC) is used as a catalyst for the synthesis of coumarin derivatives from the reaction of phenolic substrate and β- Keto-esters under solvent-free conditions. The results showed that the yield of products is between 85-94%. The advantages of this reaction include simple work-up, short reaction time, excellent yields as well as easily separation of catalyst. The catalyst can be reused several times in subsequent reactions without any decreasing in the catalyst reactivity.
https://icc.journals.pnu.ac.ir/article_2202_8574722bbd2f1d8102e602f95394d48b.pdf
(Carboxy-3-oxopropylamino)-3-propylsilylcellulose
Solvent-free condition
Phenolic substrate
β- Keto-ester
eng
Iranian chemical communication
2423-4958
2345-4806
2016-07-01
4
Issue 3, pp. 236-358, Serial No. 12
309
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2203
Oxidative aromatization of some 1,4-dihydropyridine derivatives using NaBrO3
Masoomeh Abdoli-Senejani
abdoli1356@yahoo.com
1
Nilufar Foruzan
niloofarforuzan@yahoo.com
2
Mahnaz Bahmani
bahmanimahnaz@hotmail.com
3
Tahereh Momeni Isfahani
mi_momeni@yahoo.com
4
Saba Dustepour
saba_doosti_90@yahoo.com
5
Azad university of arak
Department of chemistry, Islamic Azad university-Arak Branch
Department of chemistry, Islamic Azad university-Arak Branch
Department of chemistry, Islamic Azad university-Arak Branch
Department of chemistry, Islamic Azad university-Arak Branch
In this study, oxidation of some 3,5-diacyl or 3,5-diester 1,4-dihydropyridines to corresponding pyridine derivatives using sodium bromate in the presence of NH4Cl, NaHSO4 and Bu4NHSO4 under thermal conditions has been investigated. The yield and structure of formed products is similar under all conditions; however, the reaction is accelerated in the presence of Bu4NHSO4 and NaHSO4. In addition, oxidation of 3,5-diester 1,4-dihydropyridines, against 3,5-diacetyl 1,4-dihydropyridines using sodium bromate in the presence of tetrabutylammonium hydrogen sulfate, leads to the corresponding pyridines in shorter reaction times than sodium hydrogen sulfate. The cheapness of reagent, high yielding, easy work up and mild condition make this method a useful addition to the available methods in organic synthesis
https://icc.journals.pnu.ac.ir/article_2203_b129b38dfa13e54dfc68e26619c9e775.pdf
1,4-Dihydropyridine
aromatization
sodium bromate
eng
Iranian chemical communication
2423-4958
2345-4806
2016-07-01
4
Issue 3, pp. 236-358, Serial No. 12
318
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2218
QSAR studies and application of genetic algorithm - multiple linear regressions in prediction of novel p2x7 receptor antagonists’ activity
Alireza Banaei
alireza.banaei@gmail.com
1
Eslam Pourbasheer
ehsan.pourbasheer@gmail.com
2
Fatemeh Haggi
haggi.fateme@gmail.com
3
Department of Chemistry, Payame Noor University (PNU), P. O. Box 19395-3697
Department of Chemistry, Payame Noor University (PNU), P. O. Box 19395-3697
Department of Chemistry, Payame Noor University (PNU), P. O. Box 19395-3697, Tehran, Iran
Quantitative structure-activity relationship (QSAR) models were employed for prediction the activity of P2X7 receptor antagonists. A data set consisted of 50 purine derivatives was utilized in the model construction where 40 and 10 of these compounds were in the training and test sets respectively. A suitable group of calculated molecular descriptors was selected by employing stepwise multiple linear regressions (SW-MLR) and genetic algorithm-multiple linear regressions (GA-MLR) as variable selection tools. The proposed MLR models were fully confirmed applying internal and external validation techniques. The obtained results of this QSAR study showed the superiority of the GA-MLR model over the SW-MLR model. As a result, the obtained GA–MLR model could be applied as a valuable model for designing similar groups of P2X7 receptor antagonists.
https://icc.journals.pnu.ac.ir/article_2218_58904f61641264f060152628a967b698.pdf
QSAR
genetic algorithms
P2x7 receptor antagonists
Purine derivatives
eng
Iranian chemical communication
2423-4958
2345-4806
2016-07-01
4
Issue 3, pp. 236-358, Serial No. 12
337
346
2227
An efficient green synthesis of highly substituted imidazoles catalyzed by Al-MCM-41 nanoreactors
Abolfazl Olyaei
olyaei_a@pnu.ac.ir
1
Zohreh Derikvand
zderik@yahoo.com
2
Fatemeh Noruzian
kavir_nava@yahoo.com
3
Mahdieh Sadeghpour
m.sadeghpour@tiau.ac.ir
4
Department of Chemistry, Payame Noor University, Qazvin, Iran
bDepartment of Chemistry, Faculty of Science, Khorramabad Branch, Islamic Azad University, Khorramabad, Iran
Department of Chemistry, Payame Noor University, PO BOX 19395-3697, Tehran, I. R. of Iran Tel.: 0098-28-33224024; Fax number: 0098-28-33226400
Department of Chemistry, Takestan Branch, Islamic Azad University, Takestan, Iran
Al-MCM-41 nanoreactors is found to be a remarkable efficient catalyst for one-pot multicomponent cyclocondensation of benzil, aniline or ammonium acetate and aromatic aldehydes for the synthesis of polysubstituted imidazoles under solvent-free conditions. The reaction was efficiently promoted by 10 mg nano-Al-MCM-41 and the heterogeneous catalyst was recycled for four runs in this reaction without losing its catalytic activity. The key advantages of this process are operational simplicity, reusable catalyst, shorter reaction time, convenient work-up procedures, avoiding the use of organic solvents and purification of products by non-chromatographic methods. By this advantage, several polysubstituted imidazoles as pharmaceutical important molecules can be prepared in high yield and high purity.
https://icc.journals.pnu.ac.ir/article_2227_821dade812b4f728b46323a0d7b94bbf.pdf
Nano-Al-MCM-41
aromatic aldehyde
benzil
imidazole
aniline
eng
Iranian chemical communication
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2345-4806
2016-07-01
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2229
Surfactant-assisted synthesis of barium hexaferrite nanoparticles by hydrothermal method
Kamellia Nejati
nejati_k@yahoo.com
1
Shabnam Alizade
shaalizade@yahoo.com
2
Sara Samuey
sara_samuey@yahoo.com
3
Zolfaghar Rezvani
zrezvani@azaruniv.ac.ir
4
Department of Chemistry, Payame Noor University, P.O.BOX 19395-3697 Tehran, I.R. of Iran
Department of Chemistry, Faculty of Basic Sciences, Azarbaijan Shahid Madani University, Tabriz
Department of Chemistry, Faculty of Basic Sciences, Azarbaijan Shahid Madani University, Tabriz, Iran
Department of Chemistry, Faculty of Basic Sciences, Azarbaijan Shahid Madani University, Tabriz, Iran
In the present work, the synthesis of Barium hexaferrite (BaFe12O19) nanoparticles in thepresence of a large excess amount of OH− anions by the hydrothermal method in the presence and absence of surfactants such as Sodium dodecyl benzene sulfonate and Triton X-114 was reported. The optimized temperature in the absence of surfactant was determined (200 °C) and then Barium hexaferrite nanoparticles were synthesized by assistance of surfactants at this temperature. In this way, it was confirmed that the secondary re-crystallization can be totally suppressed with the use of surfactant and addition of surfactant leads to the synthesis of uniform and ultrafine nanoparticles with excellent superparamagnetic properties. Barium hexaferite nanoparticles have a disc-like shape. The structure, morphology and magnetic properties of samples were characterized and investigated by Powder X-ray Diffraction (PXRD), scanning electron microscopy (SEM) and vibrating sample magnetometer (VSM) techniques.
https://icc.journals.pnu.ac.ir/article_2229_ec0003f226b11032179189aa71894d68.pdf
Barium hexaferrite
hydrothermal
surfactant
Sodium dodecyl benzene sulfonate