eng
Iranian chemical communication
2423-4958
2345-4806
2014-07-01
2
Issue 3, pp. 162-231, Serial No. 4
162
167
661
One-pot and one-step novel N-methylation of 2,6-diaminopyridine
Mehdi Nabati
mnabati@ymail.com
1
Mehrdad Mahkam
mehdi_1046@yahoo.com
2
Chemistry Department, Faculty of Science, Azarbaijan Shahid Madani University, Tabriz, Iran
Chemistry Department, Faculty of Science, Azarbaijan Shahid Madani University, Tabriz, Iran
2,6-diaminopyridine is extensively used as a pharmaceutical intermediate and a hair dye coupler as oxidation formulations. It is soluble in protic solvents. Primary and secondary amines are N-methylated by various methods such as direct alkylation of amines with Hofmann mechanism, but in many of these methods due to overalkylations, we earn a mixture of amino products. Consequently, they aren't selective in secondary amines preparation. Also, the selective synthesis of secondary amines is a problematic field in organic chemistry. 2,6-diaminopyridine can be selective N-methylated from reaction of this compound with sodium azide and orthoformic ester in low time with good yields.
https://icc.journals.pnu.ac.ir/article_661_e6ca20532f0d3d6c78ee428ab422e7f6.pdf
2,6-diaminopyridine
N-methylation
selectivity
one-pot reaction
eng
Iranian chemical communication
2423-4958
2345-4806
2014-07-01
2
Issue 3, pp. 162-231, Serial No. 4
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513
1-Carboxymethyl-3-methylimidazolium chloride {[cmmim]Cl} as an efficient catalyst for the solvent-free synthesis of bis(indolyl)methanes
Ahmad Reza Moosavi-Zare
moosavizare@yahoo.com
1
Mahdi Pouraskar-Borazjani
pooraskar192@gmail.com
2
Zahra Naz
zahranaz303@yahoo.com
3
Department of Chemistry, University of Sayyed Jamaleddin Asadabadi,
Asadabad, 6541835583, Iran.
Department of Chemistry, Payame Noor University, Iran
bDepartment of Chemistry, Payame Noor University, Iran
1-Carboxymethyl-3-methylimidazolium chloride {[cmmim]Cl} is utilized as a highly efficient and reusable catalyst for the synthesis of bis(indolyl)methanes by the condensation reaction of indole with arylaldehydes under solvent-free conditions at room temperature. In summary, the presented method have several advantages including simplicity, low cost, generality, efficiency, clean reaction profile, high yield, short reaction time, ease of product isolation, mild reaction conditions, and good agreement with the green chemistry protocols. In this work, all aldehydes, including benzaldehyde and arylaldehydes possessing electron-withdrawing substituents, electron-releasing substituents and halogens on their aromatic ring, afforded the desired bis(indolyl)metanes in high to excellent yields and in short reaction times.
https://icc.journals.pnu.ac.ir/article_513_0753ee8138a9d0eb7e20762e7b60a4e0.pdf
1-Carboxymethyl-3-methylimidazolium chloride {[cmmim]Cl}
imidazolium salt
bis(indolyl)methane
indole
arylaldehyde
solvent-free
eng
Iranian chemical communication
2423-4958
2345-4806
2014-07-01
2
Issue 3, pp. 162-231, Serial No. 4
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749
Effects of structure and number of Heteroatom on the π-π stacking interactions of benzene with N-substituted coronenes: A theoretical study
Pouya Karimi
p.karimi@uoz.ac.ir
1
Mahmoud Sanchooli
sanchooli52@yahoo.com
2
Department of Chemistry, Faculty of science
University of Zabol, Zabol, Iran
Department of Chemistry, Faculty of science,
University of Zabol, Zabol, Iran
Stability of the π-π stacking interactions in the Ben||N-substituted-coronene complexes was studied using the computational quantum chemistry methods (where Ben is benzene and || denotes π-π stacking interaction, and N-substituted-coronene is coronene molecule which substituted with different number of N atoms). The results reveal simultaneous effects of structure and number of Heteroatom on the π-π stacking interactions with N-substituted-coronenes. Changing the number of Heteroatom N in N-substituted-coronenes and substitution of 8N-coronene with electron-withdrawing or electron-donating X groups alter the electron charge density at rings of this molecule and leads to different binding energies in the Ben||X-8N-substituted-coronene complexes. Results indicate that electron-withdrawing groups lead to higher π–π stacking binding energies compared to electron-donating ones in the Ben||X-8N-substituted-coronene complexes.
https://icc.journals.pnu.ac.ir/article_749_3dbc0817bd9449295fdf2500432705a7.pdf
π-π stacking interaction
benzene
N-substituted-coronene
electron charge density
binding energy
eng
Iranian chemical communication
2423-4958
2345-4806
2014-07-01
2
Issue 3, pp. 162-231, Serial No. 4
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778
Ag nanoparticle/melamine sulfonic acid supported on silica gel as an efficient catalytic system for synthesis of dihydropyrimidin thiones
Parya Nasehi
1
Alireza Kiasat
2
Mohammad Kazem Mohammadi
mkmohamadi@yahoo.com
3
Department of chemistry, Science and Research Branch, Islamic Azad University, Ahvaz, Iran
Department of chemistry, Science and Research Branch, Islamic Azad University, Ahvaz, Iran
Islamic Azad University , Ahvaz Branch
3,4-dihydropyrimidin-2(1H)-thiones were synthesized in the presence of Ag nanoparticle/melamine sulfonic acid (MSA) supported on silica gel. The reaction was carried out at 110 oC for 20 min under solvent free conditions. In all cases, the three component reaction proceeded smoothly to give the corresponding 3,4-dihydropyrimidin-2(1H)-thiones in moderate to good yield. We have found the best conditions are using 0.2 g MSA, 0.05 g Ag nanoparticle.SiO2 under solvent free conditions at 110 oC. This method have some advantages such as good yield, mild reaction conditions, ease of operation and work up, short reaction time and high product purity. In this work, we have investigated the application of Ag nanoparticle/MSA.SiO2 for synthesis of Biginelli – type condensation.
https://icc.journals.pnu.ac.ir/article_778_c682a797f1c3b0ae09c658e4213392ec.pdf
Nanoparticle melamine sulfonic acid.SiO2
Biginelli reaction
3
4-dihydropyrimidin-2(1H)-thione
solvent free
eng
Iranian chemical communication
2423-4958
2345-4806
2014-07-01
2
Issue 3, pp. 162-231, Serial No. 4
187
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782
Caesium carbonate as a highly efficient catalyst for the synthesis of macrocyclic diamides
Esmael Rostami
esmrostami@yahoo.com
1
Maryam Bagherzadeh
maryam.bagherzadeh@ymail.com
2
Akram Khodadadi
akram.khodadadi@yahoo.com
3
Ay Soda Ghobadpoor
i.ghobadpoor@yahoo.com
4
Fatemeh Dehghani
f.dehghani00@gmail.com
5
Zahra Heidari
zheidari@yahoo.com
6
Mahmood Feraidooni
mahmoodferaidooni@yahoo.com
7
Zahra Abshirini
zabshirini@yahoo.com
8
Fatemeh Tavazo
fatemeh_tavazo@yahoo.com
9
Zahra Keshvarz
z.keshavarz1385@yahoo.com
10
Department of Chemistry, Payame Noor University, Tehran, P.O. Box 19395-4697, Iran
Department of Chemistry, Payame Noor University, Tehran, P.O. Box 19395-4697, Iran
Department of Chemistry, Payame Noor University, Tehran, P.O. Box 19395-4697, Iran
Department of Chemistry, Payame Noor University, Tehran, P.O. Box 19395-4697, Iran
Department of Chemistry, Payame Noor University, Tehran, P.O. Box 19395-4697, Iran
Department of Chemistry, Payame Noor University, Tehran, P.O. Box 19395-4697, Iran
Department of Chemistry, Payame Noor University, Tehran, P.O. Box 19395-4697, Iran
Department of Chemistry, Payame Noor University, Tehran, P.O. Box 19395-4697, Iran
Department of Chemistry, Payame Noor University, Tehran, P.O. Box 19395-4697, Iran
Department of Chemistry, Payame Noor University, Tehran, P.O. Box 19395-4697, Iran
In this research work, we report the synthesis of macrocyclic diamides from the reaction of diesters and aliphatic diamines in the presence of caesium carbonate. It has been demonstrated that among the carbonate of alkali metals (Li2CO3, Na2CO3, K2CO3 and CS2CO3), CS2CO3 appear to be the best catalyst for macrocyclization. Diesters with different substitution patterns on the aromatic ring reacted smoothly with diamines under optimal conditions, affording the corresponding macrocycles in high yields. Introducing a rigid group (e.g., sulfone) on the substrate led to somewhat decreased yield. Various substrates proved to be suitable for this macrocyclization reaction, especially, the flexible ones.
https://icc.journals.pnu.ac.ir/article_782_c4b49d2f055b63cf134cced2c9d9fd58.pdf
Macrocyclic diamide
aza oxa thia crown
Synthesis
macrocycle and caesium carbonate (CS2CO3).
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eng
Iranian chemical communication
2423-4958
2345-4806
2014-07-01
2
Issue 3, pp. 162-231, Serial No. 4
196
208
788
Synthesis, characterization and swelling behavior investigation of gelatin-g-Poly(Acrylic Acid-co-Itaconic Acid)
Hossein Hosseinzadeh
h_hoseinzadeh@pnu.ac.ir
1
Mojtaba Abbasian
m_abbasian20@yahoo.com
2
Shadi Hassanzadeh
shadi_hassanzade@yahoo.com
3
Payame Noor University
Payame Noor University
Payame Noor University
A novel pH-responsive superabsorbent hydrogel based on gelatin was prepared through crosslinking copolymerization of poly (acrylic acid) and poly (itaconic acid). The copolymerization conditions including monomers, initiator, gelatin and crosslinker concentration, reaction temperature, and neutralization percent were systematically optimized to achieve a hydrogel with swelling capacity as high as possible. The hydrogels structure was confirmed using Fourier-transform infrared, thermogravimetric analysis, differential scanning calorimetric and scanning electron microscopy. The swelling of the superabsorbing hydrogel was examined in buffer solutions with pH ranged 3-12. Moreover, the swelling of the hydrogel was conducted in 0.15 M aqueous solutions of NaCl, CaCl2, and AlCl3. Due to the high swelling capacity in salt solutions, the hydrogel may be referred to as "low-salt sensitive" superabsorbent.
https://icc.journals.pnu.ac.ir/article_788_62cf10b14ffb7b3a239a3796e4800b64.pdf
Superabsorbent
hydrogel
acrylic acid
itaconic acid
swelling behavior
eng
Iranian chemical communication
2423-4958
2345-4806
2014-07-01
2
Issue 3, pp. 162-231, Serial No. 4
209
221
789
The computational study of adsorption of carbon monoxide on pristine and Ge-doped (6,0) zigzag models of BNNTs
Mahdi Rezaei Sameti
mrsameti@gmail.com
1
Nina Alisafarzadeh
2
Physical chemistry departement, Facualty science
Department of Applied Chemistry, Faculty of Science, Malayer University, Malayer, 65174, Iran
The aim of this research is studying the effects of Ge-doped on CO adsorption on the outer and inner surfaces of (6, 0) zigzag model of boron nitride nanotube (BNNTs) by using DFT theory. For this purpose, eight models of CO adsorption on the surfaces of BNNTs are considered. At first step, all structures were optimized at B3LYP and 6-31G (d) standard base set and then the electronic structure, adsorption energy, HOMO - LUMO orbitals, gap energy, quantum molecular descriptors, and NQR parameters were determined. The bond lengths neighborhood sites of Ge-doped of BNNTs at all models were increased and the bond angles decreased. The small adsorption energy value and large interaction distance show that the adsorption of CO on BNNTs is weakly physical adsorption due to weak Van der Waals interaction. Our calculated results show that the adsorption of CO on the surface of undoped models is more favorable than Ge-doped models. The NQR parameters of the first layer in all the models are larger than those other layers.
https://icc.journals.pnu.ac.ir/article_789_e4c984d1507f5dcb898fdcde5c9836a2.pdf
Boron nitride nanotube
density function theory
adsorption CO
Ge-doped
NQR
eng
Iranian chemical communication
2423-4958
2345-4806
2014-07-01
2
Issue 3, pp. 162-231, Serial No. 4
222
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790
The effect of sulfuric acid on pore initiation in anodic alumina formed in oxalic acid
Behnam Hafezi
hafezi_behnam@yahoo.com
1
Faculty of Chemistry and Petrochemical Engineering, Standard Research Institute (SRI), Karaj P. O. Box 31745-139, Iran.
In this work, a tracer study on pore initiation in anodic alumina in oxalic acid was performed. Effects of some experimental parameters such as applied electrical potential, electrolyte composition and heat pretreatment were evaluated. Electrochemical and morphological experiments were performed using potentiostatic anodizing and scanning electron microscopy (SEM) techniques, respectively. Effect of electrolyte composition on current density was discussed. In various electrical potentials, electrolyte composition had different effects on current density. Addition of sulfuric acid into oxalic acid increased porosity. Also, distribution of pore size and pore diameter were influenced by presence of sulfuric acid. Effect of electrolyte composition on the morphology of aluminum surface layer was depended on to the electric potential. Current density and porosity of aluminum surface layer was decreased by heat pretreatment.
https://icc.journals.pnu.ac.ir/article_790_355529e69300186646df1244dbd93491.pdf
Thin Films
anodized aluminum oxide
porosity
electrolyte composition