Solid state synthesis of NiO nanoparticles from [(1,2-bis(2-formyl-3-methoxyphenyl)propane)nickel(II)] chloride

Dehno Khalaji, Aliakbar; Gharib, Fatemeh

Document Type : Original Research Article

Authors

Department of Chemistry, Faculty of Science, Golestan University, Gorgan, Iran

Abstract

In this paper, nickel oxide (NiO) nanoparticles have been prepared by solid state thermal decomposition of an acyclic nickel(II) complex (1,2-bis(2-formyl-3-methoxyphenyl)propane)nickel(II) chloride, [NiL]Cl2, in an electrical furnace at optimal temperature, 450 ºC for 3.5 h. The nickel(II) complex is obtained via solid state synthesis using nickel(II) chloride and tetradentate O4 acyclic ligand 1,2-bis(2-formyl-3-methoxyphenyl)propane. The structure and morphology of NiO nanoparticles are characterized by Fourier transform infrared spectroscopy (FT-IR), powder X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). XRD and TEM analysis show that NiO nanoparticles have pure and cubic phase with the average size of 5-10 nm.

Graphical Abstract

Keywords

Main Subjects

Nanochemistry

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Iranian chemical communication

Solid state synthesis of NiO nanoparticles from [(1,2-bis(2-formyl-3-methoxyphenyl)propane)nickel(II)] chloride

References

References

Volume 4, Issue 3, pp. 236-358, Serial No. 12
July 2016
Pages 265-272

Solid state synthesis of NiO nanoparticles from [(1,2-bis(2-formyl-3-methoxyphenyl)propane)nickel(II)] chloride

References

References

Volume 4, Issue 3, pp. 236-358, Serial No. 12July 2016Pages 265-272

Volume 4, Issue 3, pp. 236-358, Serial No. 12
July 2016
Pages 265-272