Organic chemistry
Phthalimide-N-sulfonic acid and Isatin-N-sulfonic acid as highly efficient catalysts for the synthesis of bis-coumarins

Abdolkarim Zare; Jalal Sanjideh

Volume 7, Issue 2, pp. 90-159, Serial No. 23 , April 2019, , Pages 139-145

https://doi.org/10.30473/icc.2018.4612

Abstract
  Two highly efficient protocols for the production of bis-coumarins under solvent-free conditions have been introduced. The reaction of 4-hydroxycoumarin (2 eq.) with arylaldehydes (1 eq.) using phthalimide-N-sulfonic acid (PhtSA) or isatin-N-sulfonic acid (IsSA), as solid-acid catalysts, afforded the ...  Read More

Phthalimide-N-sulfonic acid and Isatin-N-sulfonic acid as highly efficient catalysts for the synthesis of bis-coumarins


Organic chemistry
[BMIm]BF4-LiCl as an effective catalytic system for the synthesis of dicoumarols

Seyyedeh Cobra Azimi; Kurosh Rad-Moghadam

Volume 3, Issue 4, pp. 283-387, Serial No. 9 , October 2015, , Pages 356-366

Abstract
  A homogeneous ionic liquid 1-butyl-3-methylimidazolium tetrafluoroborate doped with LiCl ([BMIm]BF4-LiCl) was found as catalyst solvents for the synthesis of dicoumarols by the condensation of 4-hydroxycoumarin and aldehyde at 80 ˚C. In this field, several types of aromatic aldehyde, containing electron-withdrawing ...  Read More

[BMIm]BF4-LiCl as an effective catalytic system for the synthesis of dicoumarols