Melamine trisulfonic acid as a highly efficient catalyst for the synthesis of 14-aryl-14H-dibenzo[a,j]xanthenes under solvent-free conditions

Abdolkarim Zare; Fatemeh Monfared

Volume 2, Issue 1, pp. 1-81, Serial No. 2 , January 2014, , Pages 1-17

Abstract
  Melamine trisulfonic acid (MTSA) is utilized as a highly efficient catalyst for the solvent-free condensation reaction of 2-naphthol (2 eq.) with arylaldehydes (1 eq.) under conventional thermal as well as microwave conditions to give the d  Read More

Melamine trisulfonic acid as a highly efficient catalyst for the synthesis of 14-aryl-14H-dibenzo[a,j]xanthenes under solvent-free conditions


Organic chemistry
Furocoumarins from Heracleum rawianum in Iran

Fatemeh Mahmoudi Kordi; Hassan Valizadeh; Zahra Hosseinzadeh; Mir Babak Bahadori

Volume 3, Issue 1, pp. 1-71, Serial No.6 , January 2015, , Pages 1-5

Abstract
  The species Heracleum rawianum belongs to Apiaceae, is one of the native species in Iran. The leaves and fruits of Heracleum rawianium are used traditionally in Iran as flavouring agent and spice for food. In the present work, the extraction of aerial parts of this plant with acetone by maceration is ...  Read More

Furocoumarins from Heracleum rawianum in Iran


Physical chemistry
The effects of F2 adsorption on NMR parameters of undoped and 3C-doped (8, 0) zigzag BPNTs

Mahdi Rezaei Sameti; Etrat alsadat Dadfar

Volume 4, Issue 1, pp. 1-132, Serial No. 10 , January 2016, , Pages 1-12

Abstract
  In this research, we studied the structure, properties and NMR parameters of interaction F2 gas with pristine and 3C-doped (8, 0) zigzag models of boron phosphide nanotubes (BPNTs). in order to reach these aims, we considered four different configurations for adsorption of F2gas on the outer and inner ...  Read More

The effects of F2 adsorption on NMR parameters of undoped and 3C-doped (8, 0) zigzag BPNTs


Inorganic chemistry
Comparison of chelating ability of dipeptide (histidine-β-alanine) and (tetrakis(4-sulfonatophenyl)porphyrin) (TPPS4) for in vitro removal of toxic metals

Rahmatollah Rahimi; Maryam Khosravi; Mahboubeh Rabbani; Ebrahim Safavi

Volume 6, Issue 1, pp. 1-108, Serial No. 18 , January 2018, , Pages 1-7

Abstract
  Peptides are one of the best candidates for drug development due to their high specificity and low toxicity and porphyrins are significant macromolecules in biological systems with important roles. In this works ynthesis of dipeptide (histidine-β-alanine) was done by solid-phase peptide synthesis ...  Read More

Comparison of chelating ability of dipeptide (histidine-β-alanine) and (tetrakis(4-sulfonatophenyl)porphyrin) (TPPS4) for in vitro removal of toxic metals


Organic chemistry
Multivariate curve resolution-alternating least squares applied to kinetic spectrophotometric data for the determination of mixtures of aliphatic amines

Masoumeh Hasani; Tayebeh Sayarpour; Abbas Karami; Masoud Shariati-rad

Volume 7, Issue 1, pp. 1-89, Serial No. 22 , January 2019, , Pages 1-14

https://doi.org/10.30473/icc.2018.42439.1478

Abstract
  Kinetic spectrophotometric second order data based on the reaction of 1,2-naphthoquinone-4-sulphonate (NQS) coupled with multivariate curve resolution-alternating least squares (MCR-ALS) has been proposed for simultaneous determination of ethylamine, propylamine and butylamine. Using second-order advantage, ...  Read More

Multivariate curve resolution-alternating least squares applied to kinetic spectrophotometric data for the determination of mixtures of aliphatic amines


Analytical chemistry
Electrosynthesis and optical modeling of ZnO nanostructures

Narges Ajami; Ali Ehsani; Ferydon Babaei; Ashraf Heidaripour

Volume 3, Issue 2, pp. 72-147, Serial No. 7 , April 2015, , Pages 72-77

Abstract
  Optical modeling was applied for obtaining absorbance spectra and band gap values for different morphology of ZnO semiconductor. In optical modeling, the relative permittivity scalars of zinc oxide coral like nanorods were calculated using the Bruggeman homogenization formalism. ZnO nano rods (ZONRs) ...  Read More

Electrosynthesis and optical modeling of ZnO nanostructures


Theoretical evaluation of medicinal properties for some of N-aryl-3-hydroxypyridine-4-ones derivative compounds

Mohsen Oftadeh; Lotfollah Saghaie; Shahla Pirialam

Volume 2, Issue 2, pp. 82-163, Serial No. 3 , April 2014, , Pages 82-92

Abstract
  Today, the bidentate ligands 3-hydroxypyridin-4-ones (HPOs) as orally active iron chelating agents have been demonstrated to possess potential for treatment of some human diseases such as iron-overload in thalassaemic patients and malaria. In this research, a series of HPOs with different substitutes ...  Read More

Theoretical evaluation of medicinal properties for some of N-aryl-3-hydroxypyridine-4-ones derivative compounds


Organic chemistry
Electrocatalytic multicomponent assembling of aldehydes, dimedone and 1-naphthylamine for synthesis of novel tetrahydrobenzo[c]acridin-8(7H)-one derivatives

Mohammad Reza Poor Heravi; Hassan Karami; Bagher Mohammadi; Vahid Azizkhani

Volume 7, Issue 2, pp. 90-159, Serial No. 23 , April 2019, , Pages 90-98

https://doi.org/10.30473/icc.2018.4162

Abstract
  An efficient and convenient synthesis of novel tetrahydrobenzo[c]acridin-8(7H)-one derivatives is described using the electrogenerated anion of acetonitriles as the base in the presence of tetrabutylammonium fluoride as an effective supporting electrolyte in a one-pot, three-component condensation of ...  Read More

Electrocatalytic multicomponent assembling of aldehydes, dimedone and 1-naphthylamine for synthesis of novel tetrahydrobenzo[c]acridin-8(7H)-one derivatives


Organic chemistry
Ultrasound assisted oxidation of various alcohols to corresponding aldehydes by using Al2O3 as catalyst

Sadegh Rahmati; Ardeshir Khazaei; Maryam Golbaghi; Mohammad Panahimehr

Volume 6, Issue 2, pp. 109-217, Serial No. 19 , April 2018, , Pages 109-113

Abstract
  A convenient approach for oxidation of structurally diverse alcohols has been developed using KMnO4 as oxidant agent in the presence of a catalytic amount of Al2O3 in aqueous acetonitrile. In this method various alcohols generally afforded the corresponding carbonyl compounds directly in good to high ...  Read More

Ultrasound assisted oxidation of various alcohols to corresponding aldehydes by using Al2O3 as catalyst


Organic chemistry
N,N,N,N-Tetramethylguanidinium acetate as an efficient and reusable ionic liquid catalyst for the one-pot synthesis of dihydropyrrol-2-ones

Seyed Sajad Sajadikhah

Volume 5, Issue 2, pp. 121-236, Serial No. 15 , April 2017, , Pages 121-128

Abstract
  An extremely facile and efficient procedure which has been developed for the synthesis of dihydropyrrol-2-ones. One-pot four-component reaction of amines, dialkyl acetylenedicarboxylates and formaldehyde in the presence of N,N,N,N-tetramethylguanidinium acetate [TMG][Ac] in methanol at ambient temperature ...  Read More

N,N,N,N-Tetramethylguanidinium acetate as an efficient and reusable ionic liquid catalyst for the one-pot synthesis of dihydropyrrol-2-ones


Inorganic chemistry
Synthesis, spectroscopic investigation and coductometry of a new hexadentate symmetric Schiff base ligand containing N2O2S2 donor atoms and related complexes with Cd(II), Zn(II), Co(II) and Mn (II) metal ions

Reza Golbedaghi; Ehsan Alavipour

Volume 4, Issue 2, pp. 133-235, Serial No. 11 , April 2016, , Pages 133-141

Abstract
  In this paper, we report the synthesis and characterization of a new symmetric macroacyclic Schiff base ligand (H2L) and related complexes with different metals. (H2L) was synthesized by the one pot condensation reaction of 2-[2-(2-formyl phenoxy)ethoxy]benzaldehyde and 2-aminobenzenethiol in a 1:2 molar ...  Read More

Synthesis, spectroscopic investigation and coductometry of a new hexadentate symmetric Schiff base ligand containing N2O2S2 donor atoms and related complexes with Cd(II), Zn(II), Co(II) and Mn (II) metal ions


Organic chemistry
N1,N1,N2,N2-Tetramethyl-N1,N2-bis(sulfo)ethane-1,2-diaminium chloride as a highly efficient catalyst for synthesis of some nitrogen- and oxygen-containing heterocyclic compounds

Maryam Dashtizadeh; Maryam Khalili; Fatemeh Reghbat; Eshagh Abdi; Zahra Bahadori; Zahra Sadripour; Abdolkarim Zare; Khadijeh Didehban; Seyed Sajad Sajadikhah

Volume 7, Issue 3, pp. 160-229, Serial No. 24 , July 2019, , Pages 160-173

https://doi.org/10.30473/icc.2018.40557.1441

Abstract
  In this research, a Brønsted acidic ionic liquid namely N1,N1,N2,N2-tetramethyl-N1,N2-bis(sulfo)ethane-1,2-diaminium chloride {[TMBSED][Cl]2} was employed as a highly efficient catalyst for the solvent-free production of some nitrogen- and oxygen-containing heterocyclic compounds including: (i) ...  Read More

N1,N1,N2,N2-Tetramethyl-N1,N2-bis(sulfo)ethane-1,2-diaminium chloride as a highly efficient catalyst for synthesis of some nitrogen- and oxygen-containing heterocyclic compounds


Organic chemistry
One-pot and one-step novel N-methylation of 2,6-diaminopyridine

Mehdi Nabati; Mehrdad Mahkam

Volume 2, Issue 3, pp. 162-231, Serial No. 4 , July 2014, , Pages 162-167

Abstract
  2,6-diaminopyridine is extensively used as a pharmaceutical intermediate and a hair dye coupler as oxidation formulations. It is soluble in protic solvents. Primary and secondary amines are N-methylated by various methods such as direct alkylation of amines with Hofmann mechanism, but in many of these ...  Read More

One-pot and one-step novel N-methylation of 2,6-diaminopyridine


Organic chemistry
Microwave-assisted solvent-free synthesis and antibacterial evaluation of 1-azabicyclo[3.1.0]hexane-3-enes

Bagher Mohammadi; Ebrahim Rezaei; Fouzieh Moghadami

Volume 6, Issue 3, pp. 218-324, Serial No. 20 , July 2018, , Pages 218-227

Abstract
  This work described a simple and efficient method for the synthesis of 1-azabicyclo[3.1.0]hexane-3-ene derivatives. arylidenmalononitriles and hydroxylamine hydrochloride in the presence of NaOH, under microwave irradiation and solvent-free conditions produced the titled compounds in good to excellent ...  Read More

Microwave-assisted solvent-free synthesis and antibacterial evaluation of 1-azabicyclo[3.1.0]hexane-3-enes


Organic chemistry
Friedel-Crafts alkylation of indoles with epoxides using PW12-APTES@SBA-15

Hamid Aliyan

Volume 7, Issue 4. pp. 230-306, Serial No. 25 , October 2019, , Pages 230-238

https://doi.org/10.30473/icc.2018.3871

Abstract
  H3PW12O40 (PW12) was immobilized over mesoporous alumina through the reaction of mesoporous alumina functionalized 3-aminopropyl triethoxy silane (3-APTES) and PW12. The surface properties of the functionalized nanocomposite was analyzed by a series of characterization techniques like elemental analysis, ...  Read More

Friedel-Crafts alkylation of indoles with epoxides using PW12-APTES@SBA-15


Organic chemistry
Isolation and characterization of curcumin from powdered rhizomes of turmeric plant marketed in Maragheh city of Iran with soxhlet technique

Mehdi Nabati; Mehrdad Mahkam; Hassan Heidari

Volume 2, Issue 4, pp. 236-325, Serial No. 5 , October 2014, , Pages 236-243

Abstract
  Turmeric (Curcuma longa L.) is extensively used as a spice, food preservative and colouring material. It has been used in traditional medicine for various diseases. Curcumin, the main yellow bioactive component of turmeric has been shown to have a wide spectrum of biological actions. Heretofore, it has ...  Read More

Isolation and characterization of curcumin from powdered rhizomes of turmeric plant marketed in Maragheh city of Iran with soxhlet technique


Applied Chemistry
Synthesis and characterization of Schiff-base polymer derived from 2,5-dichloroaniline and 2-hydroxybenzaldehyde

Milad Kazemnejadi; Aliakbar Dehno Khalaji; Hossein Mighani

Volume 5, Issue 3, pp. 237-363, Serial No. 16 , July 2017, , Pages 237-241

Abstract
  Schiff base sal-2,5-Clan = 2-(2,5-dichlorobenzylideneamino)phenol used as a new precursor for preparation of poly-2-(2,5-dichlorobenzylideneamino)phenol (PDCBAP). In an aqueous alkaline medium, NaOCl oxidant is capable of oxidative poly-condensation reaction (OP). Both sal-2,5-Clan and PDCBAP were characterized ...  Read More

Synthesis and characterization of Schiff-base polymer derived from 2,5-dichloroaniline and 2-hydroxybenzaldehyde


Organic chemistry
The anti cancer effects of Stachys Lavandulifolia extract

Mehdi Foruzani; Abbas Ali Dehpour; Mahla Musavi

Volume 3, Issue 4, pp. 283-387, Serial No. 9 , October 2015, , Pages 283-290

Abstract
  Stachys is one of the largest genera in the flowering plant family. It is in the subfamily Lamioideae (Labiatae), spreading and growing in different parts of Iran. The purpose of this study was to investigate the chemical properties of Stachyslavandulifolia as well as the essence, ethanol and methanol ...  Read More

The anti cancer effects of Stachys Lavandulifolia extract


Biochemistry
Essential oil composition of Cleome heratensis (Capparaceae) at different growing stages

Mohammad Ali Nasseri; Soheila Behravesh; Ali Allahresani

Volume 5, Issue 4, pp. 364-493, Serial No. 17 , October 2017, , Pages 364-371

Abstract
  In this study, the essential oil content in the aerial parts of Cleome heratensis which is growing in the east of Iran was investigated. The aerial parts of the plant were collected from the late August to October 2014, for a total of four harvests (S1-S4). Essential oils were isolated by hydro-distillation. ...  Read More

Essential oil composition of Cleome heratensis (Capparaceae) at different growing stages


Organic chemistry
The preparation of quinoxaline and 2,3-dihydropyrazine derivatives using selectfluor as an efficient and reusable catalyst

Seyedeh Fatemeh Hojati; Zahra Nematdoust; Toktam Zeinali

Volume 3, Issue 1, pp. 1-71, Serial No.6 , January 2015, , Pages 6-15

Abstract
  Selectfluor [1-(chloro methyl) -4-flouro -1,4-di azonia bicyclo[2,2,2] octane bis (tetraflouro-borate)] catalyzed the preparation of quinoxaline and 2,3-dihydo pyrazine derivatives through one -pot condensation of 1,2-di amines with 1,2-di carbonyls in solvent and under solvent- free conditions. This ...  Read More

The preparation of quinoxaline and 2,3-dihydropyrazine derivatives using selectfluor as an efficient and reusable catalyst


Analytical chemistry
Preconcentration of acrylamide with dispersive liquid-liquid microextraction based on solidification of floating organic drop prior to determination by HPLC

Shaghayegh Mohebi; Ali Mazloomifar

Volume 6, Issue 1, pp. 1-108, Serial No. 18 , January 2018, , Pages 8-18

Abstract
  A novel, rapid, simple and sensitive dispersive liquid-liquid microextraction method based on the solidification of floating organic drop (DLLME-SFO) combined with high performance liquid chromatography-ultra violet detection (HPLC-UV) was used to determine acrylamide in potato chips. The derivation ...  Read More

Preconcentration of acrylamide with dispersive liquid-liquid microextraction based on solidification of floating organic drop prior to determination by HPLC


Organic chemistry
Solvent-free and one-pot Biginelli synthesis of 3,4-dihydropyrimidin-2(1H)-ones and 3,4-dihydropyrimidin-2(1H)-thiones using ionic liquid N,N-diethyl-N-sulfoethanammonium chloride {[Et3N–SO3H]Cl} as a green catalyst

Saeid Azimi; Marziyeh Hariri

Volume 4, Issue 1, pp. 1-132, Serial No. 10 , January 2016, , Pages 13-20

Abstract
  In this work, the ionic liquid triethylamine-bonded sulfonic acid {[Et3N–SO3H]Cl}, N,N-diethyl-N-sulfoethanammonium chloride was used as a green acidic homogeneous catalyst to synthesis of 3,4-dihydropyrimidin-2(1H)-ones and 3,4-dihydropyrimidin-2(1H)-thiones as two categories of heterocycles, ...  Read More

Solvent-free and one-pot Biginelli synthesis of 3,4-dihydropyrimidin-2(1H)-ones and 3,4-dihydropyrimidin-2(1H)-thiones using ionic liquid N,N-diethyl-N-sulfoethanammonium chloride {[Et3N–SO3H]Cl} as a green catalyst


Nanochemistry
Performance comparison of graphene and graphene oxide-supported palladium nanoparticles as a highly efficient catalyst in oxygen reduction

Mir Reza Majidi; Seyran Ghaderi

Volume 6, Issue 3, pp. 218-324, Serial No. 20 , July 2018, , Pages 15-28

Abstract
  In this work, the performance of graphene nanosheets (GNs) and graphene oxide (GO) nanosheets, as a support for palladium nanoparticles (PdNPs) toward oxygen reduction reaction (ORR), was studied. The graphene nanosheets were functionalized by a new and simple method. The PdNPs were synthesized on a ...  Read More

Performance comparison of graphene and graphene oxide-supported palladium nanoparticles as a highly efficient catalyst in oxygen reduction


One-pot synthesis of highly regioselective β-azido alcohols catalyzed by Brønsted acidic ionic liquids

Sarvin Mohammadi-Aghdam; Hadi Jabbari; Omidali Pouralimardan; Fater Divsar; Issa Amini; Sami Sajjadifar

Volume 7, Issue 1, pp. 1-89, Serial No. 22 , January 2019, , Pages 15-28

https://doi.org/10.30473/icc.2019.7646

Abstract
  In this protocol, 3-(2-carboxybenzoyl)-1-methyl-1H-imidazol-3-ium chloride [Cbmim]Cl and sulfonic acid functionalized pyridinium chloride [pyridine-SO3H]Cl as a new, reusable, and green Brønsted acidic ionic liquid (BAIL) catalyst were synthesized and successfully used for the one-pot ring opening ...  Read More

Organic chemistry
Synthesis and characterization of derived imines from 4-imino-5,6,7,8-tetrahydro-1-benzothieno[2,3-d]pyrimidin-3(4H)-amine

Mehdi Soleimany; Jalil Lari; Hooshang Vahedi

Volume 2, Issue 1, pp. 1-81, Serial No. 2 , January 2014, , Pages 18-26

Abstract
  The synthesis and characterization of derived imines from 4-imino-5,6,7,8-tetrahydro-1-benzo thieno[2,3-d]pyrimidin-3(4H)-amine 3 has been developed in 3 steps through the reaction of heteroaromatic o-aminonitrile 1 with triethyl orthoformate afforded the corresponding imido ester 2 followed by cyclization ...  Read More

Synthesis and characterization of derived imines from 4-imino-5,6,7,8-tetrahydro-1-benzothieno[2,3-d]pyrimidin-3(4H)-amine